Andrey Khalimon

2024

Aminophosphine PN^H complexes of Mn(I), Fe(II), and Co(II) and evaluation of their activities in the transfer hydrogenation of nitriles

Slamova, A., Bizhanova, A., Talimonyuk, O., Gudun, K. A., Tussupbayev, S., Dmitrienko, A., Kassymbek, A., Lyssenko, K. A. & Khalimon, A. Y., 2024, In: Dalton Transactions. 53, 41, p. 16861-16870 10 p.

Research output: Contribution to journal › Article › peer-review

Aminophosphine PNH complexes of Mn(I), Fe(II), and Co(II) and evaluation of their catalytic activities in transfer hydrogenation of nitriles

Khalimon, A. Y., Bizhanova, A., Talimonyuk, O., Slamova, A. & Gudun, K., Aug 2024, p. Paper ID: 4102091.

Research output: Contribution to conference › Abstract

Characterization of humic acid salts and their use for CO2 reduction

Spietz, T., Kazankapova, M., Dobras, S., Kassenova, Z., Yermagambet, B., Khalimon, A. Y. & Stelmach, S., Sept 2024, In: Minerals. 14, 23 p., 947.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Citations (Scopus)

Metal-Free Ammonia Borane-Catalyzed Hydroboration of Lactones and Esters to Alcohols

Yessengazin, A., Seisenkul, B., Tussupbayev, S., Andizhanova, T. & Khalimon, A. Y., 2024, In: ChemCatChem. 16, 20, 7 p., e202400876.

Research output: Contribution to journal › Article › peer-review

Open Access

2 Citations (Scopus)

Metal-free catalytic hydroborative cleavage of esters and lactones

Seisenkul, B., Yessengazin, A., Tussupbayev, S., Andizhanova, T. & Khalimon, A. Y., May 2024, p. ID: 4083010.

Research output: Contribution to conference › Abstract

2023

Homogeneous Metal-Catalyzed Hydrogenation of CO2 Derivatives: Towards Indirect Conversion of CO2 to Methanol

Andizhanova, T., Adilkhanova, A. & Khalimon, A. Y., Jul 15 2023, In: Inorganics. 11, 33 p., 302.

Research output: Contribution to journal › Review article › peer-review

Open Access

File

7 Citations (Scopus)

56 Downloads (Pure)

Nickel phosphinite pincer complexes as catalysts for deoxygenative hydroboration of amides to amines

Yessengazin, A., Adilkhanova, A., Frolova, V. & Khalimon, A. Y., Mar 2023.

Research output: Contribution to conference › Abstract

Open Access

File

29 Downloads (Pure)

Ni-PCP and Ni-PCN catalysts for deoxygenative hydroboration and transfer hydrogenation reactions

Khalimon, A. Y., Adilkhanova, A., Yessengazin, A. & Gudun, K., Sept 2023.

Research output: Contribution to conference › Abstract

Open Access

File

224 Downloads (Pure)

Synthesis and Catalytic Performance of Nickel Phosphinite Pincer Complexes in Deoxygenative Hydroboration of Amides

Adilkhanova, A., Frolova, V., Yessengazin, A., Oztopcu, O., Gudun, K., Segizbayev, M., Matsokin, N., Dmitrienko, A., Pilkington, M. & Khalimon, A. Y., Feb 7 2023, In: Dalton Transactions. 52, 9, p. 2872-2886 15 p.

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

2022

Cobalt-Catalyzed Deoxygenative Hydroboration of Nitro Compounds and Applications to One-Pot Synthesis of Aldimines and Amides

Gudun, K., Zakarina, R., Segizbayev, M., Hayrapetyan, D., Slamova, A. & Khalimon, A. Y., Feb 1 2022, In: Advanced Synthesis and Catalysis. 364, 3, p. 601-611 11 p.

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Hydroboration of Isocyanates: Cobalt-Catalyzed vs. Catalyst-Free Approaches

Gudun, K., Tussupbayev, S., Slamova, A. & Khalimon, A. Y., Aug 31 2022, In: Organic and Biomolecular Chemistry. 20, 34, p. 6821-6830 10 p.

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

2021

Deoxygenative hydroboration of amides catalyzed by POCN pincer complexes of Nickel(II)

Adilkhanova, A., Frolova, V., Gudun, K. & Khalimon, A., May 17 2021. 2 p.

Research output: Contribution to conference › Abstract

Open Access

File

114 Downloads (Pure)

Deoxygenative Hydroboration of Carboxamides: A Versatile and Selective Synthetic Approach to Amines

Khalimon, A. Y., Nov 2021, In: Dalton Transactions. 50, 47, p. 17455-17466 12 p.

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Efficient cobalt-catalyzed hydroboration of nitriles and nitro compounds to N-borylamines and their use in C-N bond forming reactions

Khalimon, A., Gudun, K., Hayrapetyan, D., Slamova, A. & Zakarina, R., Aug 2021.

Research output: Contribution to conference › Abstract

Recent advances in homogeneous base-metal-catalyzed transfer hydrogenation reactions

Baidilov, D., Hayrapetyan, D. & Khalimon, A. Y., Oct 8 2021, In: Tetrahedron. 98, 132435.

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

2020

Catalytic Nitrile Hydroboration: A Route to N,N‐Diborylamines and Uses Thereof

Hayrapetyan, D. & Khalimon, A., Jul 6 2020, In: Chemistry - An Asian Journal. 15, 17, p. 2575-2587 12 p., 10.1002/asia.202000672.

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Efficient Co-catalyzed Double Hydroboration of Nitriles: Application to One-Pot Conversion of Nitriles to Aldimines

Gudun, K., Slamova, A., Hayrapetyan, D. & Khalimon, A., Feb 29 2020, In: Chemistry - A European Journal. 26, 22, p. 4963-4968 5 p., 10.1002/chem.202000753.

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Transfer Hydrogenation of Aldehydes and Ketones Catalyzed by an Aminophosphinite POCNH Pincer Complex of Ni(II)

Segizbayev, M., Oztopcu, O., Hayrapetyan, D., Shakhman, D., Lyssenko, K. & Khalimon, A., Jul 31 2020, In: Dalton Transactions. 49, 34, p. 11950-11957 7 p., 10.1039/D0DT02264K.

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

2019

Base metal catalysts for deoxygenative reduction of amides to amines

Khalimon, A., Gudun, K. A. & Hayrapetyan, D., Jun 2019, In: Catalysts. 9, 6, 26 p., 10.3390/catal9060490.

Research output: Contribution to journal › Article › peer-review

Open Access

35 Citations (Scopus)

Bench-Stable Cobalt Pre-Catalysts for Mild Hydrosilative Reduction of Tertiary Amides to Amines and Beyond

Nurseiit, A., Janabel, J., Gudun, K., Kassymbek, A., Segizbayev, M., Seilkhanov, T. & Khalimon, A., Jan 2019, In: ChemCatChem. 11, 2, p. 790-798 9 p., 10.1002/cctc.201801605.

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Efficient Co-catalyzed Double Hydroboration of Nitriles: Application to One-Pot Conversion of Nitriles to Aldimines

Gudun, K., Slamova, A., Hayrapetyan, D. & Khalimon, A., 2019, (Unpublished) In: Angewandte Chemie - International Edition. 5 p., 201915243.

Research output: Contribution to journal › Article › peer-review

Efficient Hydroboration of Carbonyl Compounds with Iminophosphinite POCN Pincer Complexes of Nickel

Gudun, K., Segizbayev, M. & Khalimon, A., 2019.

Research output: Contribution to conference › Abstract

File

442 Downloads (Pure)

Nickel and cobalt pre-catalysts for efficient reduction of carbonyl compounds and beyond

Khalimon, A., Gudun, K., Segizbayev, M. & Nurseiit, A., 2019.

Research output: Contribution to conference › Abstract

POCN Ni(II) pincer complexes: synthesis, characterization and evaluation of catalytic hydrosilylation and hydroboration activities

Gudun, K., Segizbayev, M., Adamov, A., Plessow, P., Lyssenko, K., Balanay Padayhag, M. & Khalimon, A., Jan 1 2019, In: Dalton Transactions. 48, 5, p. 1732-1746 14 p., 10.1039/C8DT04854A.

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Synthesis of novel POCN pincer complexes of Nickel (II) and their use as hydrosilylation and hydroboration catalysts

Segizbayev, M., Gudun, K., Nikonov, G. I. & Khalimon, A., Nov 5 2019.

Research output: Contribution to conference › Abstract

Open Access

File

137 Downloads (Pure)

2018

Efficient, mild and chemoselective hydroboration of carbonyl compounds using posphinite POCN pincer complexes of Nickel(II)

Adamov, A., Gudun, K., Segizbayev, M. & Khalimon, A., Dec 10 2018.

Research output: Contribution to conference › Abstract

Open Access

File

25 Downloads (Pure)

POCN pincer complexes of Ni(II): synthesis and hydrosilylation catalysis

Gudun, K., Segizbayev, M., Adamov, A. & Khalimon, A., Mar 12 2018. 1 p.

Research output: Contribution to conference › Abstract

Open Access

File

115 Downloads (Pure)

2017

Exploring Coordination Chemistry of 1,3-substituted Azulenes

Nurseiit, A., Segizbayev, M. & Khalimon, A., May 28 2017, p. 1478. 1 p.

Research output: Contribution to conference › Abstract

Open Access

Phosphinite POCN Pincer Ligands: Synthesis and Coordination Chemistry

Gudun, K., Segizbayev, M. & Khalimon, A., Jun 15 2017, p. 21-21. 1 p.

Research output: Contribution to conference › Abstract

Open Access

2015

Imido-hydrido complexes of Mo(IV): Catalysis and mechanistic aspects of hydroboration reactions

Khalimon, A. Y., Farha, P. M. & Nikonov, G. I., 2015, In: Dalton Transactions. 44, 43, p. 18945-18956 12 p.

Research output: Contribution to journal › Article › peer-review

55 Citations (Scopus)

Photo Lewis acid generators: Photorelease of B(C₆F₅)₃ and applications to catalysis

Khalimon, A. Y., Shaw, B. K., Marwitz, A. J. V., Piers, W. E., Blackwell, J. M. & Parvez, M., 2015, In: Dalton Transactions. 44, 41, p. 18196-18206 11 p.

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

2014

Multiple coupling of silanes with imido complexes of Mo

Khalimon, A. Y., McLeod, N. A., Ignatov, S. K., Okhapkin, A. I., Kuzmina, L. G., Howard, J. A. K. & Nikonov, G. I., Jun 14 2014, In: Dalton Transactions. 43, 22, p. 8446-8453 8 p.

Research output: Contribution to journal › Article › peer-review

Open Access

5 Citations (Scopus)

Nickel-catalyzed direct carboxylation of olefins with CO₂: One-pot synthesis of α,β-unsaturated carboxylic acid salts

Huguet, N., Jevtovikj, I., Gordillo, A., Lejkowski, M. L., Lindner, R., Bru, M., Khalimon, A. Y., Rominger, F., Schunk, S. A., Hofmann, P. & Limbach, M., Dec 15 2014, In: Chemistry - A European Journal. 20, 51, p. 16858-16862 5 p.

Research output: Contribution to journal › Article › peer-review

106 Citations (Scopus)

2013

Imido-supported borohydrides of titanium, vanadium and molybdenum

Khalimon, A. Y., Peterson, E., Lorber, C., Kuzmina, L. G., Howard, J. A. K., Van Der Est, A. & Nikonov, G. I., Apr 2013, In: European Journal of Inorganic Chemistry. 12, p. 2205-2211 7 p.

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Methods and Compounds for Photo Lewis Acid Generation and Uses Thereof

Piers, W. E. (Inventor), Khalimon, A. (Inventor) & Marwitz, A. J. V. (Inventor), Oct 3 2013, IPC No. C07F 5/00 (2006.01); C07B 47/00 (2006.01); C08J 3/24 (2006.01); C08J 5/18 (2006.01); C08K 5/03 (2006.01); C08K 5/375 (2006.01); C08K 5/55 (2006.01); C08K 5/56 (2006.01), World Intellectual Property Organization International Bureau, Patent No. WO 2013/142956 A1, Mar 8 2013, Priority date Mar 28 2013, Priority No. 61/616,580

Research output: Patent

Unusual structure, fluxionality, and reaction mechanism of carbonyl hydrosilylation by silyl hydride complex [(ArN=)Mo(H)(SiH₂Ph) (PMe₃)₃]

Khalimon, A. Y., Ignatov, S. K., Okhapkin, A. I., Simionescu, R., Kuzmina, L. G., Howard, J. A. K. & Nikonov, G. I., Jun 24 2013, In: Chemistry - A European Journal. 19, 26, p. 8573-8590 18 p.

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

2012

An unexpected mechanism of hydrosilylation by a silyl hydride complex of molybdenum

Khalimon, A. Y., Ignatov, S. K., Simionescu, R., Kuzmina, L. G., Howard, J. A. K. & Nikonov, G. I., Jan 16 2012, In: Inorganic Chemistry. 51, 2, p. 754-756 3 p.

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

A photo Lewis acid generator (PhLAG): Controlled photorelease of B(C ₆F ₅) ₃

Khalimon, A. Y., Piers, W. E., Blackwell, J. M., Michalak, D. J. & Parvez, M., Jun 13 2012, In: Journal of the American Chemical Society. 134, 23, p. 9601-9604 4 p.

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Catalytic hydroboration by an imido-hydrido complex of Mo(IV)

Khalimon, A. Y., Farha, P., Kuzmin, L. G. & Nikonov, G. I., Dec 5 2012, In: Chemical Communications. 48, 3, p. 455-457 3 p.

Research output: Contribution to journal › Article › peer-review

Open Access

138 Citations (Scopus)

Mechanistic aspects of hydrosilylation catalyzed by (ArN=)Mo(H)(Cl) (PMe ₃) ₃

Khalimon, A. Y., Shirobokov, O. G., Peterson, E., Simionescu, R., Kuzmina, L. G., Howard, J. A. K. & Nikonov, G. I., Apr 2 2012, In: Inorganic Chemistry. 51, 7, p. 4300-4313 14 p.

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Photogeneration of a phosphonium alkylidene olefin metathesis catalyst

Khalimon, A. Y., Leitao, E. M. & Piers, W. E., Aug 13 2012, In: Organometallics. 31, 15, p. 5634-5637 4 p.

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

2011

Catalytic and stoichiometric reactivity of β-silylamido agostic complex of Mo: Intermediacy of a silanimine complex and applications to multicomponent coupling

Khalimon, A. Y., Simionescu, R. & Nikonov, G. I., May 11 2011, In: Journal of the American Chemical Society. 133, 18, p. 7033-7053 21 p.

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

2009

Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis

Peterson, E., Khalimon, A. Y., Simionescu, R., Kuzmina, L. G., Howard, J. A. K. & Nikonov, G. I., Jan 28 2009, In: Journal of the American Chemical Society. 131, 3, p. 908-909 2 p.

Research output: Contribution to journal › Article › peer-review

96 Citations (Scopus)

β-agostic silylamido and silyl-hydrido compounds of molybdenum and tungsten

Ignatov, S. K., Khalimon, A. Y., Rees, N. H., Razuvaev, A. G., Mountford, P. & Nikonov, G. I., 2009, In: Inorganic Chemistry. 48, 20, p. 9605-9622 18 p.

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

2008

Agostic NSi-H⋯Mo complexes: From curiosity to catalysis

Khalimon, A. Y., Simionescu, R., Kuzmina, L. G., Howard, J. A. K. & Nikonov, G. I., Sept 22 2008, In: Angewandte Chemie - International Edition. 47, 40, p. 7701-7704 4 p.

Research output: Contribution to journal › Article › peer-review

Open Access

46 Citations (Scopus)

Synthesis and molecular and electronic structure of an unusual paramagnetic borohydride complex Mo(NAr)₂(PMe₃)₂(η ²-BH₄)

Khalimon, A. Y., Holland, J. P., Kowalczyk, R. M., McInnes, E. J. L., Green, J. C., Mountford, P. & Nikonov, G. I., Feb 4 2008, In: Inorganic Chemistry. 47, 3, p. 999-1006 8 p.

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

2007

Persistent silylium ions stabilized by polyagostic Si-H⋯Si interactions

Khalimon, A. Y., Zi, H. L., Simionescu, R., Vyboishchikov, S. F. & Nikonov, G. I., 2007, In: Angewandte Chemie - International Edition. 46, 24, p. 4530-4533 4 p.

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Synthesis and structural studies of germyl and germyl/stannyl substituted tungstenocenes

Khalimon, A. Y., Dorogov, K. Y., Churakov, A. V., Kuzmina, L. G., Lemenovskii, D. A., Howard, J. A. K. & Nikonov, G. I., 2007, In: Dalton Transactions. 23, p. 2440-2449 10 p.

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Andrey Khalimon, PhD

Research output

Search results