A novel hierarchically porous polypyrrole sphere modified separator for Lithium-sulfur batteries

Baoe Li, Zhenghao Sun, Yan Zhao, Zhumabay Bakenov

Research output: Contribution to journalArticle

Abstract

The commercialization of Lithium-sulfur batteries was limited by the polysulfide shuttle effect, and modifying the routine separator was an effective method to solve this problem. In this work, a novel hierarchically porous polypyrrole sphere (PPS) was successfully prepared by using silica as hard-templates. As-prepared PPS was slurry-coated on the separator, which could reduce the polarization phenomenon of the sulfur cathode, and efficiently immobilize polysulfides. As expected, high sulfur utilization was achieved by suppressing the shuttle effect. When tested in the lithium-sulfur battery, it exhibited a high capacity of 855 mAh·g-1 after 100 cycles at 0.2 C, and delivered a reversible capacity of 507 mAh·g-1 at 3 C, showing excellent electrochemical performance.

Original languageEnglish
Article number1344
JournalPolymers
Volume11
Issue number8
DOIs
Publication statusPublished - Aug 1 2019

Fingerprint

Polysulfides
Polypyrroles
Separators
Sulfur
Silicon Dioxide
Cathodes
Silica
Polarization
Lithium sulfur batteries
polypyrrole
polysulfide

Keywords

  • Electrochemical performance
  • Hierarchically porous polypyrrole sphere
  • Lithium-sulfur batteries
  • Separator
  • Shuttle effect

ASJC Scopus subject areas

  • Chemistry(all)
  • Polymers and Plastics

Cite this

A novel hierarchically porous polypyrrole sphere modified separator for Lithium-sulfur batteries. / Li, Baoe; Sun, Zhenghao; Zhao, Yan; Bakenov, Zhumabay.

In: Polymers, Vol. 11, No. 8, 1344, 01.08.2019.

Research output: Contribution to journalArticle

@article{e49bb9272b4f455ca18aed95b390a457,
title = "A novel hierarchically porous polypyrrole sphere modified separator for Lithium-sulfur batteries",
abstract = "The commercialization of Lithium-sulfur batteries was limited by the polysulfide shuttle effect, and modifying the routine separator was an effective method to solve this problem. In this work, a novel hierarchically porous polypyrrole sphere (PPS) was successfully prepared by using silica as hard-templates. As-prepared PPS was slurry-coated on the separator, which could reduce the polarization phenomenon of the sulfur cathode, and efficiently immobilize polysulfides. As expected, high sulfur utilization was achieved by suppressing the shuttle effect. When tested in the lithium-sulfur battery, it exhibited a high capacity of 855 mAh·g-1 after 100 cycles at 0.2 C, and delivered a reversible capacity of 507 mAh·g-1 at 3 C, showing excellent electrochemical performance.",
keywords = "Electrochemical performance, Hierarchically porous polypyrrole sphere, Lithium-sulfur batteries, Separator, Shuttle effect",
author = "Baoe Li and Zhenghao Sun and Yan Zhao and Zhumabay Bakenov",
year = "2019",
month = "8",
day = "1",
doi = "10.3390/polym11081344",
language = "English",
volume = "11",
journal = "Polymers",
issn = "2073-4360",
publisher = "MDPI AG",
number = "8",

}

TY - JOUR

T1 - A novel hierarchically porous polypyrrole sphere modified separator for Lithium-sulfur batteries

AU - Li, Baoe

AU - Sun, Zhenghao

AU - Zhao, Yan

AU - Bakenov, Zhumabay

PY - 2019/8/1

Y1 - 2019/8/1

N2 - The commercialization of Lithium-sulfur batteries was limited by the polysulfide shuttle effect, and modifying the routine separator was an effective method to solve this problem. In this work, a novel hierarchically porous polypyrrole sphere (PPS) was successfully prepared by using silica as hard-templates. As-prepared PPS was slurry-coated on the separator, which could reduce the polarization phenomenon of the sulfur cathode, and efficiently immobilize polysulfides. As expected, high sulfur utilization was achieved by suppressing the shuttle effect. When tested in the lithium-sulfur battery, it exhibited a high capacity of 855 mAh·g-1 after 100 cycles at 0.2 C, and delivered a reversible capacity of 507 mAh·g-1 at 3 C, showing excellent electrochemical performance.

AB - The commercialization of Lithium-sulfur batteries was limited by the polysulfide shuttle effect, and modifying the routine separator was an effective method to solve this problem. In this work, a novel hierarchically porous polypyrrole sphere (PPS) was successfully prepared by using silica as hard-templates. As-prepared PPS was slurry-coated on the separator, which could reduce the polarization phenomenon of the sulfur cathode, and efficiently immobilize polysulfides. As expected, high sulfur utilization was achieved by suppressing the shuttle effect. When tested in the lithium-sulfur battery, it exhibited a high capacity of 855 mAh·g-1 after 100 cycles at 0.2 C, and delivered a reversible capacity of 507 mAh·g-1 at 3 C, showing excellent electrochemical performance.

KW - Electrochemical performance

KW - Hierarchically porous polypyrrole sphere

KW - Lithium-sulfur batteries

KW - Separator

KW - Shuttle effect

UR - http://www.scopus.com/inward/record.url?scp=85071154409&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85071154409&partnerID=8YFLogxK

U2 - 10.3390/polym11081344

DO - 10.3390/polym11081344

M3 - Article

AN - SCOPUS:85071154409

VL - 11

JO - Polymers

JF - Polymers

SN - 2073-4360

IS - 8

M1 - 1344

ER -