A photo Lewis acid generator (PhLAG): Controlled photorelease of B(C 6F 5) 3

Andrey Y. Khalimon; Warren E. Piers; James M. Blackwell; David J. Michalak; Masood Parvez

doi:10.1021/ja3042977

A photo Lewis acid generator (PhLAG): Controlled photorelease of B(C ₆F ₅) ₃

Andrey Y. Khalimon, Warren E. Piers, James M. Blackwell, David J. Michalak, Masood Parvez

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A molecule that releases the strong organometallic Lewis acid B(C ₆F ₅) ₃ upon irradiation with 254 nm light has been developed. This photo Lewis acid generator (PhLAG) now enables the photocontrolled initiation of several reactions catalyzed by this important Lewis acid. Herein is described the synthesis of the triphenylsulfonium salt of a carbamato borate based on a carbazole function, its establishment as a PhLAG, and the application of the photorelease of B(C ₆F ₅) ₃ to the fabrication of thin films of a polysiloxane material.

Original language	English
Pages (from-to)	9601-9604
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	23
DOIs	https://doi.org/10.1021/ja3042977
Publication status	Published - Jun 13 2012

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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abstract = "A molecule that releases the strong organometallic Lewis acid B(C 6F 5) 3 upon irradiation with 254 nm light has been developed. This photo Lewis acid generator (PhLAG) now enables the photocontrolled initiation of several reactions catalyzed by this important Lewis acid. Herein is described the synthesis of the triphenylsulfonium salt of a carbamato borate based on a carbazole function, its establishment as a PhLAG, and the application of the photorelease of B(C 6F 5) 3 to the fabrication of thin films of a polysiloxane material.",

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AU - Piers, Warren E.

AU - Blackwell, James M.

AU - Michalak, David J.

AU - Parvez, Masood

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