A Rotating Electrolyte Disc (RED) for operation in liquid metal anode SOFCs

A. Toleuova, V. Yufit, S. J.R. Simons, W. C. Maskell, D. J.L. Brett

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

A novel Rotating Electrolyte Disc (RED) apparatus has been developed to determine parameters controlling mass transport of dissolved oxygen (and other gases) and oxidised species including metal oxide in liquid metal anode SOFCs. The validity of the concept and design for high temperature studies was first demonstrated by testing the setup in an aqueous system at ambient temperature (equimolar solution of ferrous and ferric chloride in KCl as supporting electrolyte). The diffusion coefficients have been determined for Fe 2+ and Fe3+ by measuring the limiting oxidation and reduction diffusion-controlled currents. The obtained data have been compared with appropriate literature data. Preliminary testing of RED in molten tin electrodes is discussed.

Original languageEnglish
Title of host publicationECS Transactions
PublisherElectrochemical Society Inc.
Pages65-70
Number of pages6
Edition3
ISBN (Electronic)9781607685395
DOIs
Publication statusPublished - Jan 1 2013

Publication series

NameECS Transactions
Number3
Volume58
ISSN (Print)1938-5862
ISSN (Electronic)1938-6737

ASJC Scopus subject areas

  • Engineering(all)

Fingerprint Dive into the research topics of 'A Rotating Electrolyte Disc (RED) for operation in liquid metal anode SOFCs'. Together they form a unique fingerprint.

  • Cite this

    Toleuova, A., Yufit, V., Simons, S. J. R., Maskell, W. C., & Brett, D. J. L. (2013). A Rotating Electrolyte Disc (RED) for operation in liquid metal anode SOFCs. In ECS Transactions (3 ed., pp. 65-70). (ECS Transactions; Vol. 58, No. 3). Electrochemical Society Inc.. https://doi.org/10.1149/05803.0065ecst