A Rotating Electrolyte Disc (RED) for operation in liquid metal anode SOFCs

A. Toleuova, V. Yufit, S. J R Simons, W. C. Maskell, D. J L Brett

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2 Citations (Scopus)

Abstract

A novel Rotating Electrolyte Disc (RED) apparatus has been developed to determine parameters controlling mass transport of dissolved oxygen (and other gases) and oxidised species including metal oxide in liquid metal anode SOFCs. The validity of the concept and design for high temperature studies was first demonstrated by testing the setup in an aqueous system at ambient temperature (equimolar solution of ferrous and ferric chloride in KCl as supporting electrolyte). The diffusion coefficients have been determined for Fe 2+ and Fe3+ by measuring the limiting oxidation and reduction diffusion-controlled currents. The obtained data have been compared with appropriate literature data. Preliminary testing of RED in molten tin electrodes is discussed.

Original languageEnglish
Title of host publicationECS Transactions
PublisherElectrochemical Society Inc.
Pages65-70
Number of pages6
Volume58
Edition3
DOIs
Publication statusPublished - 2013

Fingerprint

Solid oxide fuel cells (SOFC)
Liquid metals
Anodes
Electrolytes
Testing
Dissolved oxygen
Tin
Molten materials
Mass transfer
Oxidation
Temperature
Electrodes
Oxides
Metals
Gases

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Toleuova, A., Yufit, V., Simons, S. J. R., Maskell, W. C., & Brett, D. J. L. (2013). A Rotating Electrolyte Disc (RED) for operation in liquid metal anode SOFCs. In ECS Transactions (3 ed., Vol. 58, pp. 65-70). Electrochemical Society Inc.. https://doi.org/10.1149/05803.0065ecst

A Rotating Electrolyte Disc (RED) for operation in liquid metal anode SOFCs. / Toleuova, A.; Yufit, V.; Simons, S. J R; Maskell, W. C.; Brett, D. J L.

ECS Transactions. Vol. 58 3. ed. Electrochemical Society Inc., 2013. p. 65-70.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Toleuova, A, Yufit, V, Simons, SJR, Maskell, WC & Brett, DJL 2013, A Rotating Electrolyte Disc (RED) for operation in liquid metal anode SOFCs. in ECS Transactions. 3 edn, vol. 58, Electrochemical Society Inc., pp. 65-70. https://doi.org/10.1149/05803.0065ecst
Toleuova A, Yufit V, Simons SJR, Maskell WC, Brett DJL. A Rotating Electrolyte Disc (RED) for operation in liquid metal anode SOFCs. In ECS Transactions. 3 ed. Vol. 58. Electrochemical Society Inc. 2013. p. 65-70 https://doi.org/10.1149/05803.0065ecst
Toleuova, A. ; Yufit, V. ; Simons, S. J R ; Maskell, W. C. ; Brett, D. J L. / A Rotating Electrolyte Disc (RED) for operation in liquid metal anode SOFCs. ECS Transactions. Vol. 58 3. ed. Electrochemical Society Inc., 2013. pp. 65-70
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