TY - JOUR
T1 - Agostic NSi-H⋯Mo complexes
T2 - From curiosity to catalysis
AU - Khalimon, Andrey Y.
AU - Simionescu, Razvan
AU - Kuzmina, Lyudmila G.
AU - Howard, Judith A.K.
AU - Nikonov, Georgii I.
PY - 2008/9/22
Y1 - 2008/9/22
N2 - An uncommon catalyst: The β-agostic NSi-H⋯complex 1 (Ar=2,6-diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of Si-C coupling, such as 2.
AB - An uncommon catalyst: The β-agostic NSi-H⋯complex 1 (Ar=2,6-diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of Si-C coupling, such as 2.
KW - Agostic interactions
KW - Homogeneous catalysis
KW - Hydrosilylation
KW - Imido ligands
KW - Silicon
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U2 - 10.1002/anie.200802147
DO - 10.1002/anie.200802147
M3 - Article
C2 - 18767092
AN - SCOPUS:54749134141
VL - 47
SP - 7701
EP - 7704
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 40
ER -