Agostic NSi-H⋯Mo complexes

From curiosity to catalysis

Andrey Y. Khalimon, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A K Howard, Georgii I. Nikonov

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

An uncommon catalyst: The β-agostic NSi-H⋯complex 1 (Ar=2,6-diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of Si-C coupling, such as 2.

Original languageEnglish
Pages (from-to)7701-7704
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number40
DOIs
Publication statusPublished - Sep 22 2008
Externally publishedYes

Fingerprint

Unsaturated compounds
Hydrosilylation
Nitriles
Alkenes
Catalysis
Olefins
Catalysts

Keywords

  • Agostic interactions
  • Homogeneous catalysis
  • Hydrosilylation
  • Imido ligands
  • Silicon

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Agostic NSi-H⋯Mo complexes : From curiosity to catalysis. / Khalimon, Andrey Y.; Simionescu, Razvan; Kuzmina, Lyudmila G.; Howard, Judith A K; Nikonov, Georgii I.

In: Angewandte Chemie - International Edition, Vol. 47, No. 40, 22.09.2008, p. 7701-7704.

Research output: Contribution to journalArticle

Khalimon, AY, Simionescu, R, Kuzmina, LG, Howard, JAK & Nikonov, GI 2008, 'Agostic NSi-H⋯Mo complexes: From curiosity to catalysis', Angewandte Chemie - International Edition, vol. 47, no. 40, pp. 7701-7704. https://doi.org/10.1002/anie.200802147
Khalimon, Andrey Y. ; Simionescu, Razvan ; Kuzmina, Lyudmila G. ; Howard, Judith A K ; Nikonov, Georgii I. / Agostic NSi-H⋯Mo complexes : From curiosity to catalysis. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 40. pp. 7701-7704.
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