Agostic NSi-H⋯Mo complexes: From curiosity to catalysis

Andrey Y. Khalimon; Razvan Simionescu; Lyudmila G. Kuzmina; Judith A.K. Howard; Georgii I. Nikonov

doi:10.1002/anie.200802147

Agostic NSi-H⋯Mo complexes: From curiosity to catalysis

Andrey Y. Khalimon, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A.K. Howard, Georgii I. Nikonov

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

An uncommon catalyst: The β-agostic NSi-H⋯complex 1 (Ar=2,6-diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of Si-C coupling, such as 2.

Original language	English
Pages (from-to)	7701-7704
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	40
DOIs	https://doi.org/10.1002/anie.200802147
Publication status	Published - Sep 22 2008

Keywords

Agostic interactions
Homogeneous catalysis
Hydrosilylation
Imido ligands
Silicon

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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AU - Nikonov, Georgii I.

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