Abstract
An uncommon catalyst: The β-agostic NSi-H⋯complex 1 (Ar=2,6-diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of Si-C coupling, such as 2.
| Original language | English |
|---|---|
| Pages (from-to) | 7701-7704 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 47 |
| Issue number | 40 |
| DOIs | |
| Publication status | Published - Sep 22 2008 |
| Externally published | Yes |
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Keywords
- Agostic interactions
- Homogeneous catalysis
- Hydrosilylation
- Imido ligands
- Silicon
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Agostic NSi-H⋯Mo complexes : From curiosity to catalysis. / Khalimon, Andrey Y.; Simionescu, Razvan; Kuzmina, Lyudmila G.; Howard, Judith A K; Nikonov, Georgii I.
In: Angewandte Chemie - International Edition, Vol. 47, No. 40, 22.09.2008, p. 7701-7704.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Agostic NSi-H⋯Mo complexes
T2 - From curiosity to catalysis
AU - Khalimon, Andrey Y.
AU - Simionescu, Razvan
AU - Kuzmina, Lyudmila G.
AU - Howard, Judith A K
AU - Nikonov, Georgii I.
PY - 2008/9/22
Y1 - 2008/9/22
N2 - An uncommon catalyst: The β-agostic NSi-H⋯complex 1 (Ar=2,6-diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of Si-C coupling, such as 2.
AB - An uncommon catalyst: The β-agostic NSi-H⋯complex 1 (Ar=2,6-diisopropylphenyl) catalyzes a variety of hydrosilylation reactions. Stoichiometric reactions of 1 with unsaturated compounds proceed via the silanimine intermediate A and, in the case of olefins or nitriles, give products of Si-C coupling, such as 2.
KW - Agostic interactions
KW - Homogeneous catalysis
KW - Hydrosilylation
KW - Imido ligands
KW - Silicon
UR - http://www.scopus.com/inward/record.url?scp=54749134141&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=54749134141&partnerID=8YFLogxK
U2 - 10.1002/anie.200802147
DO - 10.1002/anie.200802147
M3 - Article
VL - 47
SP - 7701
EP - 7704
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 40
ER -