An anodic method for covalent attachment of molecules to electrodes through an ethynyl linkage

Matthew V. Sheridan; Kevin Lam; William E. Geiger

doi:10.1021/ja312405h

An anodic method for covalent attachment of molecules to electrodes through an ethynyl linkage

Matthew V. Sheridan, Kevin Lam, William E. Geiger

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Electroactive organometallic molecules have been covalently attached to electrode surfaces through an ethynyl linkage. The process takes advantage of ethynyl-based radicals generated by anodic oxidation of a lithio-activated terminal ethynyl group. Electrophores containing redox-active ferrocene, cymantrene, or cobaltocenium moieties have been deposited at the one-to-three monolayer level. Both metal-based and ligand-based chemical reactions have been carried out on the surface-modified systems.

Original language	English
Pages (from-to)	2939-2942
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	8
DOIs	https://doi.org/10.1021/ja312405h
Publication status	Published - Feb 27 2013

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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N2 - Electroactive organometallic molecules have been covalently attached to electrode surfaces through an ethynyl linkage. The process takes advantage of ethynyl-based radicals generated by anodic oxidation of a lithio-activated terminal ethynyl group. Electrophores containing redox-active ferrocene, cymantrene, or cobaltocenium moieties have been deposited at the one-to-three monolayer level. Both metal-based and ligand-based chemical reactions have been carried out on the surface-modified systems.

AB - Electroactive organometallic molecules have been covalently attached to electrode surfaces through an ethynyl linkage. The process takes advantage of ethynyl-based radicals generated by anodic oxidation of a lithio-activated terminal ethynyl group. Electrophores containing redox-active ferrocene, cymantrene, or cobaltocenium moieties have been deposited at the one-to-three monolayer level. Both metal-based and ligand-based chemical reactions have been carried out on the surface-modified systems.

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An anodic method for covalent attachment of molecules to electrodes through an ethynyl linkage

Abstract

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