Abstract
In this work, a new n-type polymer based on a thiazole-diketopyrrolopyrrole unit has been synthesized through direct (hetero)arylation polycondensation. The molar mass has been optimized by systematic variation of the the monomer concentration. Optical and electrochemical properties have been studied. They clearly suggested that this polymer possess a high electron affinity together with a very interesting absorption band, making it a good non-fullerene acceptor candidate. As a consequence, its charge transport and photovoltaic properties in a blend with the usual P3HT electron-donating polymer have been investigated.
| Original language | English |
|---|---|
| Article number | 1270 |
| Journal | Molecules |
| Volume | 23 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - Jan 1 2018 |
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Keywords
- Direct (hetero)arylation polycondensation
- N-type polymer
- Organic solar cell
- Thiazole-based DPP
ASJC Scopus subject areas
- Analytical Chemistry
- Chemistry (miscellaneous)
- Molecular Medicine
- Pharmaceutical Science
- Drug Discovery
- Physical and Theoretical Chemistry
- Organic Chemistry
Cite this
An electron-transporting thiazole-based polymer synthesized through direct (Hetero)arylation polymerization. / Chávez, Patricia; Bulut, Ibrahim; Fall, Sadiara; Ibraikulov , Olzhas; Chochos, Christos L.; Bartringer, Jérémy; Heiser, Thomas; Lévêque, Patrick; Leclerc, Nicolas.
In: Molecules, Vol. 23, No. 6, 1270, 01.01.2018.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - An electron-transporting thiazole-based polymer synthesized through direct (Hetero)arylation polymerization
AU - Chávez, Patricia
AU - Bulut, Ibrahim
AU - Fall, Sadiara
AU - Ibraikulov , Olzhas
AU - Chochos, Christos L.
AU - Bartringer, Jérémy
AU - Heiser, Thomas
AU - Lévêque, Patrick
AU - Leclerc, Nicolas
PY - 2018/1/1
Y1 - 2018/1/1
N2 - In this work, a new n-type polymer based on a thiazole-diketopyrrolopyrrole unit has been synthesized through direct (hetero)arylation polycondensation. The molar mass has been optimized by systematic variation of the the monomer concentration. Optical and electrochemical properties have been studied. They clearly suggested that this polymer possess a high electron affinity together with a very interesting absorption band, making it a good non-fullerene acceptor candidate. As a consequence, its charge transport and photovoltaic properties in a blend with the usual P3HT electron-donating polymer have been investigated.
AB - In this work, a new n-type polymer based on a thiazole-diketopyrrolopyrrole unit has been synthesized through direct (hetero)arylation polycondensation. The molar mass has been optimized by systematic variation of the the monomer concentration. Optical and electrochemical properties have been studied. They clearly suggested that this polymer possess a high electron affinity together with a very interesting absorption band, making it a good non-fullerene acceptor candidate. As a consequence, its charge transport and photovoltaic properties in a blend with the usual P3HT electron-donating polymer have been investigated.
KW - Direct (hetero)arylation polycondensation
KW - N-type polymer
KW - Organic solar cell
KW - Thiazole-based DPP
UR - http://www.scopus.com/inward/record.url?scp=85047845597&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85047845597&partnerID=8YFLogxK
U2 - 10.3390/molecules23061270
DO - 10.3390/molecules23061270
M3 - Article
C2 - 29799506
AN - SCOPUS:85047845597
VL - 23
JO - Molecules
JF - Molecules
SN - 1420-3049
IS - 6
M1 - 1270
ER -