An electron-transporting thiazole-based polymer synthesized through direct (Hetero)arylation polymerization

Patricia Chávez; Ibrahim Bulut; Sadiara Fall; Olzhas Ibraikulov; Christos L. Chochos; Jérémy Bartringer; Thomas Heiser; Patrick Lévêque; Nicolas Leclerc

doi:10.3390/molecules23061270

An electron-transporting thiazole-based polymer synthesized through direct (Hetero)arylation polymerization

Patricia Chávez, Ibrahim Bulut, Sadiara Fall, Olzhas Ibraikulov , Christos L. Chochos, Jérémy Bartringer, Thomas Heiser, Patrick Lévêque, Nicolas Leclerc

National Laboratory Astana

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

In this work, a new n-type polymer based on a thiazole-diketopyrrolopyrrole unit has been synthesized through direct (hetero)arylation polycondensation. The molar mass has been optimized by systematic variation of the the monomer concentration. Optical and electrochemical properties have been studied. They clearly suggested that this polymer possess a high electron affinity together with a very interesting absorption band, making it a good non-fullerene acceptor candidate. As a consequence, its charge transport and photovoltaic properties in a blend with the usual P3HT electron-donating polymer have been investigated.

Original language	English
Article number	1270
Journal	Molecules
Volume	23
Issue number	6
DOIs	https://doi.org/10.3390/molecules23061270
Publication status	Published - Jan 1 2018

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Keywords

Direct (hetero)arylation polycondensation
N-type polymer
Organic solar cell
Thiazole-based DPP

ASJC Scopus subject areas

Analytical Chemistry
Chemistry (miscellaneous)
Molecular Medicine
Pharmaceutical Science
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry

Cite this

Chávez, P., Bulut, I., Fall, S., Ibraikulov , O., Chochos, C. L., Bartringer, J., Heiser, T., Lévêque, P., & Leclerc, N. (2018). An electron-transporting thiazole-based polymer synthesized through direct (Hetero)arylation polymerization. Molecules, 23(6), [1270]. https://doi.org/10.3390/molecules23061270

An electron-transporting thiazole-based polymer synthesized through direct (Hetero)arylation polymerization. / Chávez, Patricia; Bulut, Ibrahim; Fall, Sadiara; Ibraikulov , Olzhas; Chochos, Christos L.; Bartringer, Jérémy; Heiser, Thomas; Lévêque, Patrick; Leclerc, Nicolas.

In: Molecules, Vol. 23, No. 6, 1270, 01.01.2018.

Research output: Contribution to journal › Article

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10.3390/molecules23061270