An optimized integrated process for the bioleaching of a spent refinery processing catalysts

Z. Noori Felegari, B. Nematdoust Haghi, Gh Amoabediny, S. M. Mousavi, M. Amouei Torkmahalleh

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Bioleaching of spent refinery processing catalysts using adapted indigenous strains of Acidithiobacillus ferrooxidans to recover Ni and Mo, and the separation of Ni from bioleaching liquor using iron magnetic nanoparticles were optimized in this study. Bioleaching optimization was performed using central composite design (CCD) method to optimize temperature (32 to 38°C), initial pH (1.5 to 2), particle size (-30 to -190μm sieve fraction) and pulp density (0.1 to 0.5%). The maximum values for Mo and Ni extraction were determined to be 62.72 and 92.34%, respectively, at 34 °C, -90.38μm sieve fraction, 0.22 % pulp density and initial pH of 1.8 under controlled pH condition. The results of bioleaching study suggest the shaking bioreactor as a suitable tool to optimize pulp density at low values for scale up purposes. The optimum pH value for Ni adsorption from synthetically made Ni solutions was found to be 8. The Ni adsorption increased with increasing temperature and the mass of the adsorbent. The percentage of Ni adsorption from a bioleaching liquor contained 30 ppm Ni and 5g/l magnetic nanoparticles was determined to be 97% after 1 hour at 34°C and pH 8. An integrated process for bioleaching of Ni and Mo from spent catalysts and adsorption of Ni using magnetic nanoparticles has been proposed in this study.

Original languageEnglish
Pages (from-to)621-634
Number of pages14
JournalInternational Journal of Environmental Research
Volume8
Issue number3
Publication statusPublished - 2014

Keywords

  • Acidithiobacillus ferrooxidans
  • Bioleaching
  • Central composite design
  • Spent catalysts

ASJC Scopus subject areas

  • Environmental Science(all)

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