An unexpected mechanism of hydrosilylation by a silyl hydride complex of molybdenum

Andrey Y. Khalimon, Stanislav K. Ignatov, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A K Howard, Georgii I. Nikonov

Research output: Contribution to journal › Article

29 Citations (Scopus)

Abstract

Carbonyl hydrosilylation catalyzed by (ArN)Mo(H)(SiH 2Ph) (PMe 3) 3 (3) is unusual in that it does not involve the expected Si-O elimination from intermediate (ArN)Mo(SiH 2Ph)(O iPr)(PMe 3) 2 (7). Instead, 7 reversibly transfers β-CH hydrogen from the alkoxide ligand to metal.

Original languageEnglish
Pages (from-to)754-756
Number of pages3
JournalInorganic Chemistry
Volume51
Issue number2
DOIs
Publication statusPublished - Jan 16 2012
Externally publishedYes

Fingerprint

Hydrosilylation
Molybdenum
alkoxides
Hydrides
hydrides
molybdenum
Hydrogen
elimination
Metals
methylidyne
Ligands
ligands
hydrogen
metals

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Khalimon, A. Y., Ignatov, S. K., Simionescu, R., Kuzmina, L. G., Howard, J. A. K., & Nikonov, G. I. (2012). An unexpected mechanism of hydrosilylation by a silyl hydride complex of molybdenum. Inorganic Chemistry, 51(2), 754-756. https://doi.org/10.1021/ic201550a

An unexpected mechanism of hydrosilylation by a silyl hydride complex of molybdenum. / Khalimon, Andrey Y.; Ignatov, Stanislav K.; Simionescu, Razvan; Kuzmina, Lyudmila G.; Howard, Judith A K; Nikonov, Georgii I.

In: Inorganic Chemistry, Vol. 51, No. 2, 16.01.2012, p. 754-756.

Research output: Contribution to journal › Article

Khalimon, AY, Ignatov, SK, Simionescu, R, Kuzmina, LG, Howard, JAK & Nikonov, GI 2012, 'An unexpected mechanism of hydrosilylation by a silyl hydride complex of molybdenum', Inorganic Chemistry, vol. 51, no. 2, pp. 754-756. https://doi.org/10.1021/ic201550a
Khalimon AY, Ignatov SK, Simionescu R, Kuzmina LG, Howard JAK, Nikonov GI. An unexpected mechanism of hydrosilylation by a silyl hydride complex of molybdenum. Inorganic Chemistry. 2012 Jan 16;51(2):754-756. https://doi.org/10.1021/ic201550a
Khalimon, Andrey Y. ; Ignatov, Stanislav K. ; Simionescu, Razvan ; Kuzmina, Lyudmila G. ; Howard, Judith A K ; Nikonov, Georgii I. / An unexpected mechanism of hydrosilylation by a silyl hydride complex of molybdenum. In: Inorganic Chemistry. 2012 ; Vol. 51, No. 2. pp. 754-756.
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