Analysis of chemical routes and processes for production of glycerol ethers

Costin Sorin Bildea, Cristian Brunchi, Grigore Bozga

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

The feasibility of glycerol etherification is investigated, considering olefins, alcohols and ethers as co-reactants. Details are presented for the reaction between glycerol and iso-butene. Simultaneous phase and chemical equilibrium calculations show that large glycerol conversion can be obtained at a good selectivity towards the desired di-ether. The behaviour of the reactor-separation-recycle flowsheet is analyzed, demonstrating that the recycle of the mono-ether has a beneficial effect. About 1 m3 of reactor volume is necessary for producing 1 kmol/h of di-ether, while the recycle rates of glycerol and mono-ethers are kept at small values.

Original languageEnglish
Title of host publication19th European Symposium on Computer Aided Process Engineering
EditorsJacek Jezowski, Jan Thullie
Pages99-104
Number of pages6
DOIs
Publication statusPublished - Jun 26 2009

Publication series

NameComputer Aided Chemical Engineering
Volume26
ISSN (Print)1570-7946

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Keywords

  • glycerol ethers
  • phase and chemical equilibrium
  • process design

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Computer Science Applications

Cite this

Sorin Bildea, C., Brunchi, C., & Bozga, G. (2009). Analysis of chemical routes and processes for production of glycerol ethers. In J. Jezowski, & J. Thullie (Eds.), 19th European Symposium on Computer Aided Process Engineering (pp. 99-104). (Computer Aided Chemical Engineering; Vol. 26). https://doi.org/10.1016/S1570-7946(09)70017-3