Ca(OH)2 Pre-Treated Bentonite for Phosphorus Removal and Recovery From Synthetic and Real Wastewater

Giorgos Markou, Dimitris Mitrogiannis, Vassilis Inglezakis, Koenraad Muylaert, Nikolaos Koukouzas, Nikolaos Tsoukalas, Efstratios Kamitsos, Dimitrios Palles, Ioannis Baziotis

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The performance of chemically pre-treated bentonite with Ca(OH)2 toward ortho-phosphate phosphorus (OPP) removal efficiency in synthetic (inorganic) and real (anaerobically digested effluents) wastewater (WW) is evaluated. The Ca(OH)2 pre-treated bentonite displays a significant increase of OPP uptake (qe; mgPg-1 bentonite) of 40 and 15 times, reaching about 14 and 5.5mgPg-1 for synthetic and real WW, respectively. The optimum pH for OPP sorption is 7, while at higher pH values, although OPP removal is high due to the precipitation in the liquid phase, the OPP removal in solid phase, that is, sorption onto bentonite surface is less compared to pH 7. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis shows that OPP forms various complexes with co-existing ions in WW, such as apatite (with Ca2+) and struvite (with NH4+ and Mg2+). The most influential parameter of the pre-treatment is the dosage of Ca(OH)2. Concentration of 0.5M Ca(OH)2 or higher is necessary for an efficient pre-treatment. In contrast, the concentration of bentonite does not affect the pre-treatment efficiency, and a mass of 500gL-1 bentonite is found to be sufficient. The chemical pre-treatment with Ca(OH)2 renders bentonite a promising low-cost sorbent for OPP removal and recovery from WW.

Original languageEnglish
JournalClean - Soil, Air, Water
DOIs
Publication statusAccepted/In press - Jan 1 2018

Fingerprint

Bentonite
orthophosphate
bentonite
Phosphorus
Phosphates
Wastewater
phosphorus
wastewater
Recovery
Sorption
sorption
struvite
Apatites
Apatite
Sorbents
removal
X ray diffraction analysis
apatite
Effluents
scanning electron microscopy

Keywords

  • Bentonite
  • Ligand exchange
  • Phosphorus removal
  • Pre-treatment
  • Sorption

ASJC Scopus subject areas

  • Environmental Chemistry
  • Water Science and Technology
  • Pollution

Cite this

Ca(OH)2 Pre-Treated Bentonite for Phosphorus Removal and Recovery From Synthetic and Real Wastewater. / Markou, Giorgos; Mitrogiannis, Dimitris; Inglezakis, Vassilis; Muylaert, Koenraad; Koukouzas, Nikolaos; Tsoukalas, Nikolaos; Kamitsos, Efstratios; Palles, Dimitrios; Baziotis, Ioannis.

In: Clean - Soil, Air, Water, 01.01.2018.

Research output: Contribution to journalArticle

Markou, G, Mitrogiannis, D, Inglezakis, V, Muylaert, K, Koukouzas, N, Tsoukalas, N, Kamitsos, E, Palles, D & Baziotis, I 2018, 'Ca(OH)2 Pre-Treated Bentonite for Phosphorus Removal and Recovery From Synthetic and Real Wastewater', Clean - Soil, Air, Water. https://doi.org/10.1002/clen.201700378
Markou, Giorgos ; Mitrogiannis, Dimitris ; Inglezakis, Vassilis ; Muylaert, Koenraad ; Koukouzas, Nikolaos ; Tsoukalas, Nikolaos ; Kamitsos, Efstratios ; Palles, Dimitrios ; Baziotis, Ioannis. / Ca(OH)2 Pre-Treated Bentonite for Phosphorus Removal and Recovery From Synthetic and Real Wastewater. In: Clean - Soil, Air, Water. 2018.
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AU - Markou, Giorgos

AU - Mitrogiannis, Dimitris

AU - Inglezakis, Vassilis

AU - Muylaert, Koenraad

AU - Koukouzas, Nikolaos

AU - Tsoukalas, Nikolaos

AU - Kamitsos, Efstratios

AU - Palles, Dimitrios

AU - Baziotis, Ioannis

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N2 - The performance of chemically pre-treated bentonite with Ca(OH)2 toward ortho-phosphate phosphorus (OPP) removal efficiency in synthetic (inorganic) and real (anaerobically digested effluents) wastewater (WW) is evaluated. The Ca(OH)2 pre-treated bentonite displays a significant increase of OPP uptake (qe; mgPg-1 bentonite) of 40 and 15 times, reaching about 14 and 5.5mgPg-1 for synthetic and real WW, respectively. The optimum pH for OPP sorption is 7, while at higher pH values, although OPP removal is high due to the precipitation in the liquid phase, the OPP removal in solid phase, that is, sorption onto bentonite surface is less compared to pH 7. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis shows that OPP forms various complexes with co-existing ions in WW, such as apatite (with Ca2+) and struvite (with NH4+ and Mg2+). The most influential parameter of the pre-treatment is the dosage of Ca(OH)2. Concentration of 0.5M Ca(OH)2 or higher is necessary for an efficient pre-treatment. In contrast, the concentration of bentonite does not affect the pre-treatment efficiency, and a mass of 500gL-1 bentonite is found to be sufficient. The chemical pre-treatment with Ca(OH)2 renders bentonite a promising low-cost sorbent for OPP removal and recovery from WW.

AB - The performance of chemically pre-treated bentonite with Ca(OH)2 toward ortho-phosphate phosphorus (OPP) removal efficiency in synthetic (inorganic) and real (anaerobically digested effluents) wastewater (WW) is evaluated. The Ca(OH)2 pre-treated bentonite displays a significant increase of OPP uptake (qe; mgPg-1 bentonite) of 40 and 15 times, reaching about 14 and 5.5mgPg-1 for synthetic and real WW, respectively. The optimum pH for OPP sorption is 7, while at higher pH values, although OPP removal is high due to the precipitation in the liquid phase, the OPP removal in solid phase, that is, sorption onto bentonite surface is less compared to pH 7. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis shows that OPP forms various complexes with co-existing ions in WW, such as apatite (with Ca2+) and struvite (with NH4+ and Mg2+). The most influential parameter of the pre-treatment is the dosage of Ca(OH)2. Concentration of 0.5M Ca(OH)2 or higher is necessary for an efficient pre-treatment. In contrast, the concentration of bentonite does not affect the pre-treatment efficiency, and a mass of 500gL-1 bentonite is found to be sufficient. The chemical pre-treatment with Ca(OH)2 renders bentonite a promising low-cost sorbent for OPP removal and recovery from WW.

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KW - Phosphorus removal

KW - Pre-treatment

KW - Sorption

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