Catalytic hydroboration by an imido-hydrido complex of Mo(iv)

Andrey Y. Khalimon, Philip Farha, Lyudmila G. Kuzmina, Georgii I. Nikonov

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)2. The latter species easily undergoes chemoselective coupling with aldehydes R′C(O)H to yield imines RCH 2NC(H)R′.

Original languageEnglish
Pages (from-to)455-457
Number of pages3
JournalChemical Communications
Volume48
Issue number3
DOIs
Publication statusPublished - Jan 11 2012
Externally publishedYes

Fingerprint

Nitriles
Imines
Aldehydes
Amines

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Catalytic hydroboration by an imido-hydrido complex of Mo(iv). / Khalimon, Andrey Y.; Farha, Philip; Kuzmina, Lyudmila G.; Nikonov, Georgii I.

In: Chemical Communications, Vol. 48, No. 3, 11.01.2012, p. 455-457.

Research output: Contribution to journalArticle

Khalimon, Andrey Y. ; Farha, Philip ; Kuzmina, Lyudmila G. ; Nikonov, Georgii I. / Catalytic hydroboration by an imido-hydrido complex of Mo(iv). In: Chemical Communications. 2012 ; Vol. 48, No. 3. pp. 455-457.
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