Catalytic hydroboration by an imido-hydrido complex of Mo(IV)

Andrey Y. Khalimon, Philip Farha, Lyudmila G. Kuzmin, Georgii I. Nikonov

Research output: Contribution to journalArticlepeer-review

91 Citations (Scopus)

Abstract

The imido-hydrido complex (ArN)Mo(H)(Cl)(PMe3)3 catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)2. The latter species easily undergoes chemoselective coupling with aldehydes R′C(O)H to yield imines RCH2N=C(H)R′.

Original languageEnglish
Pages (from-to)455-457
Number of pages3
JournalChemical Communications
Volume48
Issue number3
DOIs
Publication statusPublished - Dec 5 2012

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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