Abstract
With an attempt to develop some supermolecular assemblies of a particular structure through a controllable method, the present study developed two distinct assembly patterns for Poly(Tannic Acid) (PTA) by means of adjusting the components and composition of a binary solvent system. The assembly mechanism was explored through the comparison of theoretical calculations and experimental results with respect to how solvent sets affect the nature of intermolecular interactions among oligomers. The results indicate that the morphology of the aggregates of PTA is determined from the nature of the intermolecular interactions among oligomers. While a cuboid shaped aggregate is likely the result of π-π stacking self-assembly, a sphere shaped morphology is formed through intermolecular hydrogen bonding among the oligomers. The results of the present work provide valuable resources to tune the aggregation morphology by quantitatively adjusting the physical properties of the binary solvent.
| Original language | English |
|---|---|
| Pages (from-to) | 4751-4758 |
| Number of pages | 8 |
| Journal | Nanoscale |
| Volume | 11 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Mar 21 2019 |
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ASJC Scopus subject areas
- Materials Science(all)
Cite this
Competitive self-assembly driven as a route to control the morphology of poly(tannic acid) assemblies. / Liu, Zhiqing; Fan, Haiyan; Li, Wei; Bai, Guoqiang; Li, Xie; Zhao, Ning; Xu, Jian; Zhou, Feng; Guo, Xuhong; Dai, Bin; Benassi, Enrico; Jia, Xin.
In: Nanoscale, Vol. 11, No. 11, 21.03.2019, p. 4751-4758.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Competitive self-assembly driven as a route to control the morphology of poly(tannic acid) assemblies
AU - Liu, Zhiqing
AU - Fan, Haiyan
AU - Li, Wei
AU - Bai, Guoqiang
AU - Li, Xie
AU - Zhao, Ning
AU - Xu, Jian
AU - Zhou, Feng
AU - Guo, Xuhong
AU - Dai, Bin
AU - Benassi, Enrico
AU - Jia, Xin
PY - 2019/3/21
Y1 - 2019/3/21
N2 - With an attempt to develop some supermolecular assemblies of a particular structure through a controllable method, the present study developed two distinct assembly patterns for Poly(Tannic Acid) (PTA) by means of adjusting the components and composition of a binary solvent system. The assembly mechanism was explored through the comparison of theoretical calculations and experimental results with respect to how solvent sets affect the nature of intermolecular interactions among oligomers. The results indicate that the morphology of the aggregates of PTA is determined from the nature of the intermolecular interactions among oligomers. While a cuboid shaped aggregate is likely the result of π-π stacking self-assembly, a sphere shaped morphology is formed through intermolecular hydrogen bonding among the oligomers. The results of the present work provide valuable resources to tune the aggregation morphology by quantitatively adjusting the physical properties of the binary solvent.
AB - With an attempt to develop some supermolecular assemblies of a particular structure through a controllable method, the present study developed two distinct assembly patterns for Poly(Tannic Acid) (PTA) by means of adjusting the components and composition of a binary solvent system. The assembly mechanism was explored through the comparison of theoretical calculations and experimental results with respect to how solvent sets affect the nature of intermolecular interactions among oligomers. The results indicate that the morphology of the aggregates of PTA is determined from the nature of the intermolecular interactions among oligomers. While a cuboid shaped aggregate is likely the result of π-π stacking self-assembly, a sphere shaped morphology is formed through intermolecular hydrogen bonding among the oligomers. The results of the present work provide valuable resources to tune the aggregation morphology by quantitatively adjusting the physical properties of the binary solvent.
UR - http://www.scopus.com/inward/record.url?scp=85062833956&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85062833956&partnerID=8YFLogxK
U2 - 10.1039/c8nr07236a
DO - 10.1039/c8nr07236a
M3 - Article
C2 - 30601558
AN - SCOPUS:85062833956
VL - 11
SP - 4751
EP - 4758
JO - Nanoscale
JF - Nanoscale
SN - 2040-3364
IS - 11
ER -