Covalent attachment of porphyrins and ferrocenes to electrode surfaces through direct anodic oxidation of terminal ethynyl groups

Matthew V. Sheridan, Kevin Lam, William E. Geiger

    Research output: Contribution to journal › Article

    21 Citations (Scopus)

    Abstract

    One with the surface: A method is presented for electrode modification with terminal alkynes and alkenes. Direct oxidation of these moieties leads to efficient grafting onto glassy carbon, gold, platinum, and indium tin oxide surfaces. Various ferrocenes and 5,10,15,20-(4-ethynylphenyl)porphyrin were attached in this way.

    Original languageEnglish
    Pages (from-to)12897-12900
    Number of pages4
    JournalAngewandte Chemie - International Edition
    Volume52
    Issue number49
    DOIs
    Publication statusPublished - Dec 2 2013

    Fingerprint

    Porphyrins
    Anodic oxidation
    Electrodes
    Alkynes
    Glassy carbon
    Alkenes
    Platinum
    Tin oxides
    Gold
    Indium
    Olefins
    Oxidation
    indium tin oxide

    Keywords

    • electrochemistry
    • electrodes
    • oxidation
    • porphyrins
    • surface chemistry

    ASJC Scopus subject areas

    • Chemistry(all)
    • Catalysis

    Cite this

    Covalent attachment of porphyrins and ferrocenes to electrode surfaces through direct anodic oxidation of terminal ethynyl groups. / Sheridan, Matthew V.; Lam, Kevin; Geiger, William E.

    In: Angewandte Chemie - International Edition, Vol. 52, No. 49, 02.12.2013, p. 12897-12900.

    Research output: Contribution to journal › Article

    Sheridan, MV, Lam, K & Geiger, WE 2013, 'Covalent attachment of porphyrins and ferrocenes to electrode surfaces through direct anodic oxidation of terminal ethynyl groups', Angewandte Chemie - International Edition, vol. 52, no. 49, pp. 12897-12900. https://doi.org/10.1002/anie.201307453
    Sheridan MV, Lam K, Geiger WE. Covalent attachment of porphyrins and ferrocenes to electrode surfaces through direct anodic oxidation of terminal ethynyl groups. Angewandte Chemie - International Edition. 2013 Dec 2;52(49):12897-12900. https://doi.org/10.1002/anie.201307453
    Sheridan, Matthew V. ; Lam, Kevin ; Geiger, William E. / Covalent attachment of porphyrins and ferrocenes to electrode surfaces through direct anodic oxidation of terminal ethynyl groups. In: Angewandte Chemie - International Edition. 2013 ; Vol. 52, No. 49. pp. 12897-12900.
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