TY - JOUR
T1 - Covalent attachment of porphyrins and ferrocenes to electrode surfaces through direct anodic oxidation of terminal ethynyl groups
AU - Sheridan, Matthew V.
AU - Lam, Kevin
AU - Geiger, William E.
PY - 2013/12/2
Y1 - 2013/12/2
N2 - One with the surface: A method is presented for electrode modification with terminal alkynes and alkenes. Direct oxidation of these moieties leads to efficient grafting onto glassy carbon, gold, platinum, and indium tin oxide surfaces. Various ferrocenes and 5,10,15,20-(4-ethynylphenyl)porphyrin were attached in this way.
AB - One with the surface: A method is presented for electrode modification with terminal alkynes and alkenes. Direct oxidation of these moieties leads to efficient grafting onto glassy carbon, gold, platinum, and indium tin oxide surfaces. Various ferrocenes and 5,10,15,20-(4-ethynylphenyl)porphyrin were attached in this way.
KW - electrochemistry
KW - electrodes
KW - oxidation
KW - porphyrins
KW - surface chemistry
UR - http://www.scopus.com/inward/record.url?scp=84888598384&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84888598384&partnerID=8YFLogxK
U2 - 10.1002/anie.201307453
DO - 10.1002/anie.201307453
M3 - Article
C2 - 24127205
AN - SCOPUS:84888598384
VL - 52
SP - 12897
EP - 12900
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 49
ER -