Abstract
One with the surface: A method is presented for electrode modification with terminal alkynes and alkenes. Direct oxidation of these moieties leads to efficient grafting onto glassy carbon, gold, platinum, and indium tin oxide surfaces. Various ferrocenes and 5,10,15,20-(4-ethynylphenyl)porphyrin were attached in this way.
| Original language | English |
|---|---|
| Pages (from-to) | 12897-12900 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 52 |
| Issue number | 49 |
| DOIs | |
| Publication status | Published - Dec 2 2013 |
Keywords
- electrochemistry
- electrodes
- oxidation
- porphyrins
- surface chemistry
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Cite this
Sheridan, M. V., Lam, K., & Geiger, W. E. (2013). Covalent attachment of porphyrins and ferrocenes to electrode surfaces through direct anodic oxidation of terminal ethynyl groups. Angewandte Chemie - International Edition, 52(49), 12897-12900. https://doi.org/10.1002/anie.201307453