Design implications of the nonlinear dynamics of the monolithic loop reactor for Fischer-Tropsch synthesis

Pietro Altimari, Costin-Sorin Bildea, Ruud Van Ommen, Johan Grievink

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The nonlinear behavior of the monolith reactor with a liquid phase recycle for Fischer-Tropsch synthesis is investigated. A dimensionless distributed heterogeneous model is developed to describe reactor dynamics and bifurcation analysis is performed by varying the coolant temperature, the reactor gas inlet flow rate and the effectiveness factor of the external heat exchanger. As system parameters vary, coexisting stationary patterns are observed. Stability analysis of the reactor steady state solution regimes is carried out and Hopf bifurcation points are identified. As a result, periodic spatiotemporal patterns are found to arise in wide regions of the parameter space. The evolution of periodic solution regimes is examined by means of numerical simulation of the reactor model. Implications for operation and control are discussed.

Original languageEnglish
Title of host publication2008 AIChE Spring National Meeting, Conference Proceedings
PublisherAmerican Institute of Chemical Engineers
ISBN (Print)9780816910236
Publication statusPublished - Jan 1 2008
Event2008 AIChE Spring National Meeting, Conference - New Orleans, LA, United States
Duration: Apr 6 2008Apr 10 2008

Other

Other2008 AIChE Spring National Meeting, Conference
CountryUnited States
CityNew Orleans, LA
Period4/6/084/10/08

Fingerprint

Fischer-Tropsch synthesis
Inlet flow
Hopf bifurcation
Coolants
Heat exchangers
Gases
Flow rate
Computer simulation
Liquids
Temperature

Keywords

  • Fischer-Tropsch
  • Hopf bifurcations
  • Monolithic reactor
  • State multiplicity

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Altimari, P., Bildea, C-S., Van Ommen, R., & Grievink, J. (2008). Design implications of the nonlinear dynamics of the monolithic loop reactor for Fischer-Tropsch synthesis. In 2008 AIChE Spring National Meeting, Conference Proceedings American Institute of Chemical Engineers.

Design implications of the nonlinear dynamics of the monolithic loop reactor for Fischer-Tropsch synthesis. / Altimari, Pietro; Bildea, Costin-Sorin; Van Ommen, Ruud; Grievink, Johan.

2008 AIChE Spring National Meeting, Conference Proceedings. American Institute of Chemical Engineers, 2008.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Altimari, P, Bildea, C-S, Van Ommen, R & Grievink, J 2008, Design implications of the nonlinear dynamics of the monolithic loop reactor for Fischer-Tropsch synthesis. in 2008 AIChE Spring National Meeting, Conference Proceedings. American Institute of Chemical Engineers, 2008 AIChE Spring National Meeting, Conference, New Orleans, LA, United States, 4/6/08.
Altimari P, Bildea C-S, Van Ommen R, Grievink J. Design implications of the nonlinear dynamics of the monolithic loop reactor for Fischer-Tropsch synthesis. In 2008 AIChE Spring National Meeting, Conference Proceedings. American Institute of Chemical Engineers. 2008
Altimari, Pietro ; Bildea, Costin-Sorin ; Van Ommen, Ruud ; Grievink, Johan. / Design implications of the nonlinear dynamics of the monolithic loop reactor for Fischer-Tropsch synthesis. 2008 AIChE Spring National Meeting, Conference Proceedings. American Institute of Chemical Engineers, 2008.
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