Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis

Erik Peterson; Andrey Y. Khalimon; Razvan Simionescu; Lyudmila G. Kuzmina; Judith A.K. Howard; Georgii I. Nikonov

doi:10.1021/ja8085388

Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis

Erik Peterson, Andrey Y. Khalimon, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A.K. Howard, Georgii I. Nikonov

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

New Imido hydride complex 1 catalyzes a variety of silylation reactions that proceed via initial substrate activation but not silane addition.

Original language	English
Pages (from-to)	908-909
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	3
DOIs	https://doi.org/10.1021/ja8085388
Publication status	Published - Jan 28 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis. / Peterson, Erik; Khalimon, Andrey Y.; Simionescu, Razvan; Kuzmina, Lyudmila G.; Howard, Judith A.K.; Nikonov, Georgii I.

In: Journal of the American Chemical Society, Vol. 131, No. 3, 28.01.2009, p. 908-909.

Research output: Contribution to journal › Article › peer-review

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