Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis

Erik Peterson, Andrey Y. Khalimon, Razvan Simionescu, Lyudmila G. Kuzmina, Judith A K Howard, Georgii I. Nikonov

Research output: Contribution to journalArticle

77 Citations (Scopus)

Abstract

New Imido hydride complex 1 catalyzes a variety of silylation reactions that proceed via initial substrate activation but not silane addition.

Original languageEnglish
Pages (from-to)908-909
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number3
DOIs
Publication statusPublished - Jan 28 2009
Externally publishedYes

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Hydrosilylation
Silanes
Molybdenum
Catalysis
Hydrides
Chemical activation
Substrates

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis. / Peterson, Erik; Khalimon, Andrey Y.; Simionescu, Razvan; Kuzmina, Lyudmila G.; Howard, Judith A K; Nikonov, Georgii I.

In: Journal of the American Chemical Society, Vol. 131, No. 3, 28.01.2009, p. 908-909.

Research output: Contribution to journalArticle

Peterson, Erik ; Khalimon, Andrey Y. ; Simionescu, Razvan ; Kuzmina, Lyudmila G. ; Howard, Judith A K ; Nikonov, Georgii I. / Diversity of catalysis by an imido-hydrido complex of molybdenum. Mechanism of carbonyl hydrosilylation and silane alcoholysis. In: Journal of the American Chemical Society. 2009 ; Vol. 131, No. 3. pp. 908-909.
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