Electrochemical synthesis of spirocyclic morpholines and tetrahydrofurans via an oxidative dearomatisation strategy

Davit Hayrapetyan; Lyailya Yussupova; Almaz Kaipov; Aigerim Galyamova

doi:10.1039/d3ob01176c

Electrochemical synthesis of spirocyclic morpholines and tetrahydrofurans via an oxidative dearomatisation strategy

Davit Hayrapetyan, Lyailya Yussupova, Almaz Kaipov, Aigerim Galyamova

Research output: Contribution to journal › Article › peer-review

Abstract

Simple and scalable electrochemical oxidation of the electron-rich benzene ring followed by intramolecular capture of reactive cation-radical intermediates opens access to spirocyclic morpholines and tetrahydrofurans. The obtained molecules can be readily modified to value-added building blocks.

Original language	English
Pages (from-to)	7090-7094
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	21
Issue number	35
DOIs	https://doi.org/10.1039/d3ob01176c
Publication status	Published - Aug 15 2023

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Electrochemical synthesis of spirocyclic morpholines and tetrahydrofurans via an oxidative dearomatisation strategy",

abstract = "Simple and scalable electrochemical oxidation of the electron-rich benzene ring followed by intramolecular capture of reactive cation-radical intermediates opens access to spirocyclic morpholines and tetrahydrofurans. The obtained molecules can be readily modified to value-added building blocks.",

author = "Davit Hayrapetyan and Lyailya Yussupova and Almaz Kaipov and Aigerim Galyamova",

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T1 - Electrochemical synthesis of spirocyclic morpholines and tetrahydrofurans via an oxidative dearomatisation strategy

AU - Hayrapetyan, Davit

AU - Yussupova, Lyailya

AU - Kaipov, Almaz

AU - Galyamova, Aigerim

PY - 2023/8/15

Y1 - 2023/8/15

N2 - Simple and scalable electrochemical oxidation of the electron-rich benzene ring followed by intramolecular capture of reactive cation-radical intermediates opens access to spirocyclic morpholines and tetrahydrofurans. The obtained molecules can be readily modified to value-added building blocks.

AB - Simple and scalable electrochemical oxidation of the electron-rich benzene ring followed by intramolecular capture of reactive cation-radical intermediates opens access to spirocyclic morpholines and tetrahydrofurans. The obtained molecules can be readily modified to value-added building blocks.

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JO - Organic and Biomolecular Chemistry

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Electrochemical synthesis of spirocyclic morpholines and tetrahydrofurans via an oxidative dearomatisation strategy

Abstract

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