Enhanced photostability of photoluminescent dye-doped solutions and polymers with the addition of dielectric-oxide micro-particles

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9 Citations (Scopus)

Abstract

Organic dye molecules in both solid polymethyl methacrylate and in solution have been found to display greatly enhanced photostability with the addition of micro-particles. Micro-particle doped poly(methyl methacrylate) samples and solutions were prepared doped with the laser dye pyrromethene 567 and rhodamine 6G. Study of the composite dye material as a gain medium in a laser provided a controlled and sensitive test of the photostability. The micro-particle doped samples used as the active laser medium demonstrated a doubling in service life to 0.4 million pulses compared with undoped samples before the output intensity was reduced to one-half. Further addition of a singlet oxygen quencher (DABCO) enhanced the photostability to 0.6 million pulses. Possible explanations discussed include cavity QED effects, surface photophysical and photochemical interactions and thermo-mechanical effects. These observations are relevant to photoluminescent devices and in general to the photostability of organic molecules.

Original languageEnglish
Pages (from-to)457-461
Number of pages5
JournalOptics Communications
Volume271
Issue number2
DOIs
Publication statusPublished - Mar 15 2007

Keywords

  • Micro-particles
  • Organic
  • PMMA
  • Photoluminescence
  • Photostability
  • Polymers
  • Pyrromethene
  • Rhodamine
  • Solid-state dye laser

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

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