Exact statistical mechanics of some classical 1D systems

Tassos Bountis, Robert H G Helleman

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The classical partition function QN is calculated in closed form for the following 1D N-body "hard-core" potentials, V = Σ i = 1 N (gxi + b/|xi - x i-1|), i.e., a Coulomb nearest neighbor "chain" in a uniform field, and V = (1/2)Σi = 0 N Σ j = 0 N exp (|xi - xj|), a "fluid" with exponential interactions. The QN for both systems is separated into a product of N, similar, tractable integrals each depending on a different value of the index i. All thermodynamic variables are obtained in closed form. In the limit, as N→∞, most of them do not linearly increase with the size of the system, i.e., they are not "extensive." This is also discussed in terms of the "stability" and "temperedness" properties of the potentials. Nevertheless, both systems do have a heat capacity which is "extensive."

Original languageEnglish
Pages (from-to)477-481
Number of pages5
JournalJournal of Mathematical Physics
Volume19
Issue number2
Publication statusPublished - 1977
Externally publishedYes

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Statistical mechanics
statistical mechanics
Statistical Mechanics
Specific heat
Thermodynamics
Fluids
Closed-form
partitions
Heat Capacity
specific heat
Partition Function
thermodynamics
fluids
Nearest Neighbor
products
Linearly
Fluid
interactions
Interaction

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Bountis, T., & Helleman, R. H. G. (1977). Exact statistical mechanics of some classical 1D systems. Journal of Mathematical Physics, 19(2), 477-481.

Exact statistical mechanics of some classical 1D systems. / Bountis, Tassos; Helleman, Robert H G.

In: Journal of Mathematical Physics, Vol. 19, No. 2, 1977, p. 477-481.

Research output: Contribution to journalArticle

Bountis, T & Helleman, RHG 1977, 'Exact statistical mechanics of some classical 1D systems', Journal of Mathematical Physics, vol. 19, no. 2, pp. 477-481.
Bountis, Tassos ; Helleman, Robert H G. / Exact statistical mechanics of some classical 1D systems. In: Journal of Mathematical Physics. 1977 ; Vol. 19, No. 2. pp. 477-481.
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