Free-standing SnSe@C nanofiber anode material for low-temperature lithium-ion batteries

Aiym Rakhmetova; Ayaulym Belgibayeva; Gulnur Kalimuldina; Arailym Nurpeissova; Zhumabay Bakenov

doi:10.1016/j.powera.2023.100128

Free-standing SnSe@C nanofiber anode material for low-temperature lithium-ion batteries

Aiym Rakhmetova
, Ayaulym Belgibayeva
, Gulnur Kalimuldina
, Arailym Nurpeissova
, Zhumabay Bakenov

Nazarbayev University

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A novel approach to develop a low-temperature lithium-ion battery (LIB) based on tin selenide (SnSe) and carbon (C) nanofibers as the active electrode material has been successfully achieved. The SnSe@C nanofiber anode exhibited excellent electrochemical properties, such as high capacity and good rate capability. The anode maintained a consistent charge capacity of ∼923 mAh g⁻¹ at a current rate of 0.1 A g⁻¹ over 100 cycles at room temperature. Furthermore, investigated for the first time at low temperatures, the SnSe@C nanofiber anode exhibited superior capacity (∼430 mAh g⁻¹ at −20 °C) compared to conventional graphite electrode (∼25 mAh g⁻¹ at −20 °C). The proposed SnSe@C nanofiber anode demonstrated a great potential to be applied for developing next-generation LIBs with improved low-temperature performance.

Original language	English
Article number	100128
Journal	Journal of Power Sources Advances
Volume	24
DOIs	https://doi.org/10.1016/j.powera.2023.100128
Publication status	Published - Oct 2023

Funding

This research was funded by the research targeted program #51763/ПЦФ-МЦРОАП РК-19 from the Ministry of Digital Development, Innovations and Aerospace Industry of the Republic of Kazakhstan. The authors thank Core facilities of Nazarbayev University for assistance in conducting the physical characterizations of samples. Special thanks go to Prof. S.S. Kim, O. Mukhan (Chungnam National University), and Dr. N. Umirov (Nazarbayev University) for TEM-EDS analysis. This research was funded by the research targeted program #51763/ПЦФ-МЦРОАП РК-19 from the Ministry of Digital Development, Innovations and Aerospace Industry of the Republic of Kazakhstan . The authors thank Core facilities of Nazarbayev University for assistance in conducting the physical characterizations of samples. Special thanks go to Prof. S.S. Kim, O. Mukhan (Chungnam National University), and Dr. N. Umirov (Nazarbayev University) for TEM-EDS analysis.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 3 Good Health and Well-being
SDG 7 Affordable and Clean Energy

Keywords

Binder free
Free-standing anode
Low-temperature lithium-ion batteries
Stannous selenide
Tin selenide

ASJC Scopus subject areas

Energy Engineering and Power Technology
Electrochemistry
Materials Chemistry

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10.1016/j.powera.2023.100128

Cite this

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title = "Free-standing SnSe@C nanofiber anode material for low-temperature lithium-ion batteries",

abstract = "A novel approach to develop a low-temperature lithium-ion battery (LIB) based on tin selenide (SnSe) and carbon (C) nanofibers as the active electrode material has been successfully achieved. The SnSe@C nanofiber anode exhibited excellent electrochemical properties, such as high capacity and good rate capability. The anode maintained a consistent charge capacity of ∼923 mAh g−1 at a current rate of 0.1 A g−1 over 100 cycles at room temperature. Furthermore, investigated for the first time at low temperatures, the SnSe@C nanofiber anode exhibited superior capacity (∼430 mAh g−1 at −20 °C) compared to conventional graphite electrode (∼25 mAh g−1 at −20 °C). The proposed SnSe@C nanofiber anode demonstrated a great potential to be applied for developing next-generation LIBs with improved low-temperature performance.",

keywords = "Binder free, Free-standing anode, Low-temperature lithium-ion batteries, Stannous selenide, Tin selenide",

author = "Aiym Rakhmetova and Ayaulym Belgibayeva and Gulnur Kalimuldina and Arailym Nurpeissova and Zhumabay Bakenov",

note = "Funding Information: This research was funded by the research targeted program \#51763/ПЦФ-МЦРОАП РК-19 from the Ministry of Digital Development, Innovations and Aerospace Industry of the Republic of Kazakhstan. The authors thank Core facilities of Nazarbayev University for assistance in conducting the physical characterizations of samples. Special thanks go to Prof. S.S. Kim, O. Mukhan (Chungnam National University), and Dr. N. Umirov (Nazarbayev University) for TEM-EDS analysis. Funding Information: This research was funded by the research targeted program \#51763/ПЦФ-МЦРОАП РК-19 from the Ministry of Digital Development, Innovations and Aerospace Industry of the Republic of Kazakhstan . The authors thank Core facilities of Nazarbayev University for assistance in conducting the physical characterizations of samples. Special thanks go to Prof. S.S. Kim, O. Mukhan (Chungnam National University), and Dr. N. Umirov (Nazarbayev University) for TEM-EDS analysis. Publisher Copyright: {\textcopyright} 2023 The Authors",

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doi = "10.1016/j.powera.2023.100128",

language = "English",

volume = "24",

journal = "Journal of Power Sources Advances",

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T1 - Free-standing SnSe@C nanofiber anode material for low-temperature lithium-ion batteries

AU - Rakhmetova, Aiym

AU - Belgibayeva, Ayaulym

AU - Kalimuldina, Gulnur

AU - Nurpeissova, Arailym

AU - Bakenov, Zhumabay

N1 - Funding Information: This research was funded by the research targeted program #51763/ПЦФ-МЦРОАП РК-19 from the Ministry of Digital Development, Innovations and Aerospace Industry of the Republic of Kazakhstan. The authors thank Core facilities of Nazarbayev University for assistance in conducting the physical characterizations of samples. Special thanks go to Prof. S.S. Kim, O. Mukhan (Chungnam National University), and Dr. N. Umirov (Nazarbayev University) for TEM-EDS analysis. Funding Information: This research was funded by the research targeted program #51763/ПЦФ-МЦРОАП РК-19 from the Ministry of Digital Development, Innovations and Aerospace Industry of the Republic of Kazakhstan . The authors thank Core facilities of Nazarbayev University for assistance in conducting the physical characterizations of samples. Special thanks go to Prof. S.S. Kim, O. Mukhan (Chungnam National University), and Dr. N. Umirov (Nazarbayev University) for TEM-EDS analysis. Publisher Copyright: © 2023 The Authors

PY - 2023/10

Y1 - 2023/10

N2 - A novel approach to develop a low-temperature lithium-ion battery (LIB) based on tin selenide (SnSe) and carbon (C) nanofibers as the active electrode material has been successfully achieved. The SnSe@C nanofiber anode exhibited excellent electrochemical properties, such as high capacity and good rate capability. The anode maintained a consistent charge capacity of ∼923 mAh g−1 at a current rate of 0.1 A g−1 over 100 cycles at room temperature. Furthermore, investigated for the first time at low temperatures, the SnSe@C nanofiber anode exhibited superior capacity (∼430 mAh g−1 at −20 °C) compared to conventional graphite electrode (∼25 mAh g−1 at −20 °C). The proposed SnSe@C nanofiber anode demonstrated a great potential to be applied for developing next-generation LIBs with improved low-temperature performance.

AB - A novel approach to develop a low-temperature lithium-ion battery (LIB) based on tin selenide (SnSe) and carbon (C) nanofibers as the active electrode material has been successfully achieved. The SnSe@C nanofiber anode exhibited excellent electrochemical properties, such as high capacity and good rate capability. The anode maintained a consistent charge capacity of ∼923 mAh g−1 at a current rate of 0.1 A g−1 over 100 cycles at room temperature. Furthermore, investigated for the first time at low temperatures, the SnSe@C nanofiber anode exhibited superior capacity (∼430 mAh g−1 at −20 °C) compared to conventional graphite electrode (∼25 mAh g−1 at −20 °C). The proposed SnSe@C nanofiber anode demonstrated a great potential to be applied for developing next-generation LIBs with improved low-temperature performance.

KW - Binder free

KW - Free-standing anode

KW - Low-temperature lithium-ion batteries

KW - Stannous selenide

KW - Tin selenide

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UR - https://www.scopus.com/pages/publications/85172256782#tab=citedBy

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DO - 10.1016/j.powera.2023.100128

M3 - Article

AN - SCOPUS:85172256782

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VL - 24

JO - Journal of Power Sources Advances

JF - Journal of Power Sources Advances

M1 - 100128

ER -

Free-standing SnSe@C nanofiber anode material for low-temperature lithium-ion batteries

Abstract

Funding

UN SDGs

Keywords

ASJC Scopus subject areas

Access to Document

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