TY - JOUR
T1 - Heterobimetallic bismuth-transition metal coordination complexes as single-source molecular precursors for the formation of advanced oxide materials
AU - Ould-Ely, Teyeb
AU - Thurston, John H.
AU - Whitmire, Kenton H.
PY - 2005/11/1
Y1 - 2005/11/1
N2 - In this manuscript we outline recent results on the synthesis of heterobimetallic coordination complexes involving bismuth and the transition elements using either bifunctional ligands or Lewis acid-base adduct formation as a synthetic strategy. Significant structural features in the molecular heterobimetallic species resulting from these two approaches are highlighted. The ability of these complexes to act as single-source precursors for the formation of advanced oxide nanomaterials has been investigated, and the potential of these complexes versus traditional methods for the formation of advanced ceramics is discussed.
AB - In this manuscript we outline recent results on the synthesis of heterobimetallic coordination complexes involving bismuth and the transition elements using either bifunctional ligands or Lewis acid-base adduct formation as a synthetic strategy. Significant structural features in the molecular heterobimetallic species resulting from these two approaches are highlighted. The ability of these complexes to act as single-source precursors for the formation of advanced oxide nanomaterials has been investigated, and the potential of these complexes versus traditional methods for the formation of advanced ceramics is discussed.
KW - Bismuth nanoparticles
KW - Heterobimetallic oxides
KW - Mixed oxides
KW - Single-source precursors
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U2 - 10.1016/j.crci.2005.04.005
DO - 10.1016/j.crci.2005.04.005
M3 - Article
AN - SCOPUS:27744458930
VL - 8
SP - 1906
EP - 1921
JO - Comptes Rendus Chimie
JF - Comptes Rendus Chimie
SN - 1631-0748
IS - 11-12
ER -