High performance Zn/LiFePO4 aqueous rechargeable battery for large scale applications

Nulati Yesibolati, Nurzhan Umirov, Aibolat Koishybay, Marzhana Omarova, Indira Kurmanbayeva, Yongguang Zhang, Yan Zhao, Zhumabay Bakenov

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

In this work, a novel aqueous rechargeable battery Zn/LiCl-ZnCl2/LiFePO4 has been developed. The electrochemical performance of olivine LiFePO4 positive electrode has been investigated in the structure of this battery. Along with a high (about 100%) coulombic efficiency, this electrode exhibited enhanced cycling performance at various current densities up to 60 C with the average operation voltage 1.2 V. A capacity of 92 mAh g-1 was achieved over 400 cycles at a cycling rate 6 C, and exhibited a superior rate capability with the capacities of 72 mAh g-1 at 30 C and 45 mAh g-1 at 60 C, respectively. The battery temperature tolerance was first investigated, and it demonstrated a very stable cycling at a wide temperature range from -10 °C to 50 °C. A cylindrical battery with the capacity of 150 mAh was first designed using proposed configuration and successfully operated under 54 mA with high efficiency and capacity retention. Zn/LiFePO4 battery offers an exceptionally safe, low cost, long cycling life, and high energy and power density energy storage for large-scale applications.

Original languageEnglish
Pages (from-to)505-511
Number of pages7
JournalElectrochimica Acta
Volume152
DOIs
Publication statusPublished - Feb 12 2014

Fingerprint

Secondary batteries
Olivine
Electrodes
Energy storage
Current density
Temperature
Electric potential
Costs
LiFePO4

Keywords

  • Aqueous rechargeable lithium-ion battery
  • Battery temperature performance
  • Lithium-Ion Battery
  • Scale-up battery

ASJC Scopus subject areas

  • Electrochemistry
  • Chemical Engineering(all)

Cite this

High performance Zn/LiFePO4 aqueous rechargeable battery for large scale applications. / Yesibolati, Nulati; Umirov, Nurzhan; Koishybay, Aibolat; Omarova, Marzhana; Kurmanbayeva, Indira; Zhang, Yongguang; Zhao, Yan; Bakenov, Zhumabay.

In: Electrochimica Acta, Vol. 152, 12.02.2014, p. 505-511.

Research output: Contribution to journalArticle

Yesibolati, Nulati ; Umirov, Nurzhan ; Koishybay, Aibolat ; Omarova, Marzhana ; Kurmanbayeva, Indira ; Zhang, Yongguang ; Zhao, Yan ; Bakenov, Zhumabay. / High performance Zn/LiFePO4 aqueous rechargeable battery for large scale applications. In: Electrochimica Acta. 2014 ; Vol. 152. pp. 505-511.
@article{6573d4d19874413a91443f75ef72e24e,
title = "High performance Zn/LiFePO4 aqueous rechargeable battery for large scale applications",
abstract = "In this work, a novel aqueous rechargeable battery Zn/LiCl-ZnCl2/LiFePO4 has been developed. The electrochemical performance of olivine LiFePO4 positive electrode has been investigated in the structure of this battery. Along with a high (about 100{\%}) coulombic efficiency, this electrode exhibited enhanced cycling performance at various current densities up to 60 C with the average operation voltage 1.2 V. A capacity of 92 mAh g-1 was achieved over 400 cycles at a cycling rate 6 C, and exhibited a superior rate capability with the capacities of 72 mAh g-1 at 30 C and 45 mAh g-1 at 60 C, respectively. The battery temperature tolerance was first investigated, and it demonstrated a very stable cycling at a wide temperature range from -10 °C to 50 °C. A cylindrical battery with the capacity of 150 mAh was first designed using proposed configuration and successfully operated under 54 mA with high efficiency and capacity retention. Zn/LiFePO4 battery offers an exceptionally safe, low cost, long cycling life, and high energy and power density energy storage for large-scale applications.",
keywords = "Aqueous rechargeable lithium-ion battery, Battery temperature performance, Lithium-Ion Battery, Scale-up battery",
author = "Nulati Yesibolati and Nurzhan Umirov and Aibolat Koishybay and Marzhana Omarova and Indira Kurmanbayeva and Yongguang Zhang and Yan Zhao and Zhumabay Bakenov",
year = "2014",
month = "2",
day = "12",
doi = "10.1016/j.electacta.2014.11.168",
language = "English",
volume = "152",
pages = "505--511",
journal = "Electrochimica Acta",
issn = "0013-4686",
publisher = "Elsevier",

}

TY - JOUR

T1 - High performance Zn/LiFePO4 aqueous rechargeable battery for large scale applications

AU - Yesibolati, Nulati

AU - Umirov, Nurzhan

AU - Koishybay, Aibolat

AU - Omarova, Marzhana

AU - Kurmanbayeva, Indira

AU - Zhang, Yongguang

AU - Zhao, Yan

AU - Bakenov, Zhumabay

PY - 2014/2/12

Y1 - 2014/2/12

N2 - In this work, a novel aqueous rechargeable battery Zn/LiCl-ZnCl2/LiFePO4 has been developed. The electrochemical performance of olivine LiFePO4 positive electrode has been investigated in the structure of this battery. Along with a high (about 100%) coulombic efficiency, this electrode exhibited enhanced cycling performance at various current densities up to 60 C with the average operation voltage 1.2 V. A capacity of 92 mAh g-1 was achieved over 400 cycles at a cycling rate 6 C, and exhibited a superior rate capability with the capacities of 72 mAh g-1 at 30 C and 45 mAh g-1 at 60 C, respectively. The battery temperature tolerance was first investigated, and it demonstrated a very stable cycling at a wide temperature range from -10 °C to 50 °C. A cylindrical battery with the capacity of 150 mAh was first designed using proposed configuration and successfully operated under 54 mA with high efficiency and capacity retention. Zn/LiFePO4 battery offers an exceptionally safe, low cost, long cycling life, and high energy and power density energy storage for large-scale applications.

AB - In this work, a novel aqueous rechargeable battery Zn/LiCl-ZnCl2/LiFePO4 has been developed. The electrochemical performance of olivine LiFePO4 positive electrode has been investigated in the structure of this battery. Along with a high (about 100%) coulombic efficiency, this electrode exhibited enhanced cycling performance at various current densities up to 60 C with the average operation voltage 1.2 V. A capacity of 92 mAh g-1 was achieved over 400 cycles at a cycling rate 6 C, and exhibited a superior rate capability with the capacities of 72 mAh g-1 at 30 C and 45 mAh g-1 at 60 C, respectively. The battery temperature tolerance was first investigated, and it demonstrated a very stable cycling at a wide temperature range from -10 °C to 50 °C. A cylindrical battery with the capacity of 150 mAh was first designed using proposed configuration and successfully operated under 54 mA with high efficiency and capacity retention. Zn/LiFePO4 battery offers an exceptionally safe, low cost, long cycling life, and high energy and power density energy storage for large-scale applications.

KW - Aqueous rechargeable lithium-ion battery

KW - Battery temperature performance

KW - Lithium-Ion Battery

KW - Scale-up battery

UR - http://www.scopus.com/inward/record.url?scp=84915792914&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84915792914&partnerID=8YFLogxK

U2 - 10.1016/j.electacta.2014.11.168

DO - 10.1016/j.electacta.2014.11.168

M3 - Article

AN - SCOPUS:84915792914

VL - 152

SP - 505

EP - 511

JO - Electrochimica Acta

JF - Electrochimica Acta

SN - 0013-4686

ER -