High-resolution 13C nuclear magnetic resonance evidence of phase transition of Rb,Cs-intercalated single-walled nanotubes

M. Bouhrara, Y. Saih, T. Wågberg, C. Goze-Bac, E. Abou-Hamad

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

We present 13 C high-resolution magic-angle-turning (MAT) and magic angle spinning nuclear magnetic resonance data of Cs and Rb intercalated single walled carbon nanotubes. We find two distinct phases at different intercalation levels. A simple charge transfer is applicable at low intercalation level. The new phase at high intercalation level is accompanied by a hybridization of alkali (s) orbitals with the carbon (sp2) orbitals of the single walled nanotubes, which indicate bundle surface sites is the most probable alkali site.

Original languageEnglish
Article number054306
JournalJournal of Applied Physics
Volume110
Issue number5
DOIs
Publication statusPublished - Sep 1 2011
Externally publishedYes

Fingerprint

intercalation
nanotubes
nuclear magnetic resonance
high resolution
alkalies
orbitals
metal spinning
bundles
carbon nanotubes
charge transfer
carbon

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

High-resolution 13C nuclear magnetic resonance evidence of phase transition of Rb,Cs-intercalated single-walled nanotubes. / Bouhrara, M.; Saih, Y.; Wågberg, T.; Goze-Bac, C.; Abou-Hamad, E.

In: Journal of Applied Physics, Vol. 110, No. 5, 054306, 01.09.2011.

Research output: Contribution to journalArticle

Bouhrara, M. ; Saih, Y. ; Wågberg, T. ; Goze-Bac, C. ; Abou-Hamad, E. / High-resolution 13C nuclear magnetic resonance evidence of phase transition of Rb,Cs-intercalated single-walled nanotubes. In: Journal of Applied Physics. 2011 ; Vol. 110, No. 5.
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