Highly Efficient Epoxidation of Cyclopentene Catalyzed by Magnetically Recoverable Mg–doped Cobalt Ferrites with Greatly Improved Performances

Jinhui Tong, Fangfang Liu, Wenhui Wang, Lili Bo, Abdulla Mahboob, Haiyan Fan

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Abstract The alkaline earth metal Mg-doped CoFe2O4 composite ferrite samples MgxCo1-xFe2O4 (x=0, 0.1, 0.3, 0.5, 0.7 and 1) were prepared using a sol-gel auto-combustion route. The as-prepared samples were characterized by Raman spectrometry, X-ray diffractometry (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), ICP?atomic emission spectroscopy and N2-physisorption. The catalytic activities of the samples were tested in the cyclopentene oxidation using hydrogen peroxide (30?%) as the oxidant. Compared with the pristine CoFe2O4 and MgFe2O4, the Mg?Co composite ferrites showed much enhanced catalytic performances in the oxidation of cyclopentene with cyclopentene oxide as the main product. In particular, 95.2?% of cyclopentene conversion and 96.3?% of selectivity for cyclopentene oxide were achieved when Mg0.5Co0.5Fe2O4 was used at 60 oC for 8?h in the oxidation reaction. The catalyst can be easily separated by applying magnetic field and exhibits great reusability.
Original languageEnglish
Pages (from-to)6356-6361
Number of pages6
JournalChemistrySelect
Volume1
Issue number20
DOIs
Publication statusPublished - Dec 9 2016

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Cyclopentanes
Epoxidation
Oxidation
Oxides
Alkaline Earth Metals
Atomic emission spectroscopy
Physisorption
Ferrites
Composite materials
Reusability
Oxidants
X ray diffraction analysis
Hydrogen Peroxide
Spectrometry
Sol-gels
Ferrite
Catalyst activity
cobalt ferrite
Magnetic fields
Transmission electron microscopy

Keywords

  • Cyclopentene epoxidation
  • Hydrogen peroxide
  • Mg−Co composite ferrites
  • Magnetic recovery

Cite this

Highly Efficient Epoxidation of Cyclopentene Catalyzed by Magnetically Recoverable Mg–doped Cobalt Ferrites with Greatly Improved Performances. / Tong, Jinhui; Liu, Fangfang; Wang, Wenhui; Bo, Lili; Mahboob, Abdulla; Fan, Haiyan.

In: ChemistrySelect, Vol. 1, No. 20, 09.12.2016, p. 6356-6361.

Research output: Contribution to journalArticle

Tong, Jinhui ; Liu, Fangfang ; Wang, Wenhui ; Bo, Lili ; Mahboob, Abdulla ; Fan, Haiyan. / Highly Efficient Epoxidation of Cyclopentene Catalyzed by Magnetically Recoverable Mg–doped Cobalt Ferrites with Greatly Improved Performances. In: ChemistrySelect. 2016 ; Vol. 1, No. 20. pp. 6356-6361.
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abstract = "Abstract The alkaline earth metal Mg-doped CoFe2O4 composite ferrite samples MgxCo1-xFe2O4 (x=0, 0.1, 0.3, 0.5, 0.7 and 1) were prepared using a sol-gel auto-combustion route. The as-prepared samples were characterized by Raman spectrometry, X-ray diffractometry (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), ICP?atomic emission spectroscopy and N2-physisorption. The catalytic activities of the samples were tested in the cyclopentene oxidation using hydrogen peroxide (30?{\%}) as the oxidant. Compared with the pristine CoFe2O4 and MgFe2O4, the Mg?Co composite ferrites showed much enhanced catalytic performances in the oxidation of cyclopentene with cyclopentene oxide as the main product. In particular, 95.2?{\%} of cyclopentene conversion and 96.3?{\%} of selectivity for cyclopentene oxide were achieved when Mg0.5Co0.5Fe2O4 was used at 60 oC for 8?h in the oxidation reaction. The catalyst can be easily separated by applying magnetic field and exhibits great reusability.",
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author = "Jinhui Tong and Fangfang Liu and Wenhui Wang and Lili Bo and Abdulla Mahboob and Haiyan Fan",
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AU - Bo, Lili

AU - Mahboob, Abdulla

AU - Fan, Haiyan

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N2 - Abstract The alkaline earth metal Mg-doped CoFe2O4 composite ferrite samples MgxCo1-xFe2O4 (x=0, 0.1, 0.3, 0.5, 0.7 and 1) were prepared using a sol-gel auto-combustion route. The as-prepared samples were characterized by Raman spectrometry, X-ray diffractometry (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), ICP?atomic emission spectroscopy and N2-physisorption. The catalytic activities of the samples were tested in the cyclopentene oxidation using hydrogen peroxide (30?%) as the oxidant. Compared with the pristine CoFe2O4 and MgFe2O4, the Mg?Co composite ferrites showed much enhanced catalytic performances in the oxidation of cyclopentene with cyclopentene oxide as the main product. In particular, 95.2?% of cyclopentene conversion and 96.3?% of selectivity for cyclopentene oxide were achieved when Mg0.5Co0.5Fe2O4 was used at 60 oC for 8?h in the oxidation reaction. The catalyst can be easily separated by applying magnetic field and exhibits great reusability.

AB - Abstract The alkaline earth metal Mg-doped CoFe2O4 composite ferrite samples MgxCo1-xFe2O4 (x=0, 0.1, 0.3, 0.5, 0.7 and 1) were prepared using a sol-gel auto-combustion route. The as-prepared samples were characterized by Raman spectrometry, X-ray diffractometry (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), ICP?atomic emission spectroscopy and N2-physisorption. The catalytic activities of the samples were tested in the cyclopentene oxidation using hydrogen peroxide (30?%) as the oxidant. Compared with the pristine CoFe2O4 and MgFe2O4, the Mg?Co composite ferrites showed much enhanced catalytic performances in the oxidation of cyclopentene with cyclopentene oxide as the main product. In particular, 95.2?% of cyclopentene conversion and 96.3?% of selectivity for cyclopentene oxide were achieved when Mg0.5Co0.5Fe2O4 was used at 60 oC for 8?h in the oxidation reaction. The catalyst can be easily separated by applying magnetic field and exhibits great reusability.

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KW - Magnetic recovery

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