Improved calculations of the lowest vibrational transitions in He H+

Sergiy Bubin, Monika Stanke, Dariusz Kdziera, Ludwik Adamowicz

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

More accurate variational calculations of the lowest three pure vibrational states (v=0,1,2) of the He4 H+ molecular ion have been carried out without assuming the Born-Oppenheimer approximation. In the calculations we included the complete set of α2 relativistic corrections, i.e., mass-velocity, Darwin, spin-spin, and orbit-orbit. This allowed us to improve the agreement between the theory and the experiment for the vibrational frequencies of the 1→0 and 2→1 transitions as compared to our previous calculations.

Original languageEnglish
Article number022512
JournalPhysical Review A - Atomic, Molecular, and Optical Physics
Volume76
Issue number2
DOIs
Publication statusPublished - Aug 30 2007
Externally publishedYes

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orbits
Born-Oppenheimer approximation
molecular ions
vibrational states

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Physics and Astronomy(all)

Cite this

Improved calculations of the lowest vibrational transitions in He H+. / Bubin, Sergiy; Stanke, Monika; Kdziera, Dariusz; Adamowicz, Ludwik.

In: Physical Review A - Atomic, Molecular, and Optical Physics, Vol. 76, No. 2, 022512, 30.08.2007.

Research output: Contribution to journalArticle

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