Lithium AlPO 4 composite polymer battery with nanostructured LiMn 2O 4 cathode

Zhumabay Bakenov, Masanobu Nakayama, Masataka Wakihara, Izumi Taniguchi

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

The borate ester plasticized AlPO 4 composite solid polymer electrolytes (SPE) have been synthesized and studied as candidates for lithium polymer battery (LPB) application. The electrochemical and thermal properties of SPE were shown to be suitable for practical LPB. Nanostructured LiMn 2O 4 with spherical particles was synthesized via ultrasonic spray pyrolysis technique and has shown a superior performance to the one prepared via conventional methods as cathode for LPB. Furthermore, the AlPO 4 addition to the polymer electrolyte has improved the polymer battery performance. Based on the AC impedance spectroscopy data, the performance improvement was suggested as being due to the cathode/polymer electrolyte interface stabilization in the presence of AlPO 4. The Li/composite polymer electrolyte/nanostructured LiMn 2O 4 electrochemical cell showed stable cyclability during the various current density tests, and its performance was found to be quite acceptable for practical utilities at ambient temperature and showed remarkable improvements at 60 °C compared with the solid state reaction counterpart.

Original languageEnglish
Pages (from-to)295-302
Number of pages8
JournalJournal of Solid State Electrochemistry
Volume12
Issue number3
DOIs
Publication statusPublished - Mar 1 2008

Keywords

  • Cathode/electrolyte interface
  • Lithium polymer batteries
  • Nanostructured lithium manganese oxide

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Electrochemistry
  • Electrical and Electronic Engineering

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