Lithium-Sulfur Batteries: State of the Art and Future Directions

Teyeb Ould Ely, Dana Kamzabek, Dhritiman Chakraborty, Michael F. Doherty

Research output: Contribution to journalReview article

34 Citations (Scopus)

Abstract

Sulfur remains in the spotlight as a future cathode candidate for the post-lithium-ion age. This is primarily due to its low cost and high discharge capacity, two critical requirements for any future cathode material that seeks to dominate the market of portable electronic devices, electric transportation, and electric-grid energy storage. However, before Li-S batteries replace lithium ion batteries, several technical challenges need to be solved. Among these challenges are polysulfide containment, the increase of sulfur loading (which must be ≥4-6 mg cm -2), the increase of sulfur fraction to ≥70%, the increase of sulfur utilization to ≥80%, the decrease of the electrolyte/sulfur weight ratio (which must be in the range of 3:1 or lower), and the stability of lithium anode material. Besides traditional carbon coating strategies, recent novel strategies addressing each of these challenges have been reported. The main purpose of this work is to review the state of the art and summarize and shed light on the most promising recent discoveries related to each challenge. This review also addresses the role of the electrolyte systems and electrocatalytic additives.

Original languageEnglish
Pages (from-to)1783-1814
Number of pages32
JournalACS Applied Energy Materials
Volume1
Issue number5
DOIs
Publication statusPublished - May 29 2018

Keywords

  • batteries beyond lithium
  • electrocatalytic polysulfides conversion
  • lithium anode protection
  • lithium-sulfur batteries
  • solid-state electrolytes
  • sulfur cathode coating

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Energy Engineering and Power Technology
  • Electrochemistry
  • Materials Chemistry
  • Electrical and Electronic Engineering

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  • Cite this

    Ould Ely, T., Kamzabek, D., Chakraborty, D., & Doherty, M. F. (2018). Lithium-Sulfur Batteries: State of the Art and Future Directions. ACS Applied Energy Materials, 1(5), 1783-1814. https://doi.org/10.1021/acsaem.7b00153