Lowest S 2 Electronic Excitations of the Boron Atom

Sergiy Bubin, Ludwik Adamowicz

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A theoretical ab initio approach for calculating bound states of small atoms is developed and implemented. The approach is based on finite-nuclear-mass [non-Born-Oppenheimer (non-BO)] nonrelativistic variational calculations performed with all-particle explicitly correlated Gaussian functions and includes the leading relativistic and quantum electrodynamics energy corrections determined using the non-BO wave functions. The approach is applied to determine the total and transition energies for the lowest four S2 electronic excitations of the boron atom. The transition energies agree with the available experimental values within 0.2-0.3 cm-1. Previously, such accuracy was achieved for three- and four-electron systems.

Original languageEnglish
Article number043001
JournalPhysical Review Letters
Volume118
Issue number4
DOIs
Publication statusPublished - Jan 27 2017

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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