Molten solvent extraction behavior of trivalent La, Sm, Dy, and Yb with tri-n-butyl phosphate into molten paraffin wax at 60°C

Bo Peng, Jinzhang Gao, Haiyan Fan, Jingwan Kang, Wu Yang

Research output: Contribution to journal › Article

Abstract

The extraction behavior of La3+, Sm3+, Dy3+, and Yb3+ in sodium acetate-acetic acid medium was studied with tri-n-buryl phosphate (TBP) at 60°C using paraffin wax as a diluent. The extraction percentage is greater than 85% in the pH range of 6 to 8. The result of slope analysis method indicates that the compositions of the extracted species is found to be La(TBP)(OH)(Ac)2 for La3+ and Yb(TBP)(OH)3 for Yb3+. The effects of extracting time, the concentration of TBP in the organic phase and salts on the extraction efficiency were also discussed.

Original languageEnglish
Pages (from-to)7-11
Number of pages5
JournalRare Metals
Volume21
Issue number1
Publication statusPublished - Mar 2002
Externally publishedYes

Fingerprint

Paraffin waxes
solvent extraction
waxes
paraffins
Solvent extraction
Molten materials
phosphates
Phosphates
Sodium Acetate
diluents
acetic acid
Acetic acid
Acetic Acid
acetates
Salts
Sodium
sodium
slopes
salts
tributyl phosphate

Keywords

  • Paraffin wax
  • Rare earth
  • Solvent extraction
  • TBP

ASJC Scopus subject areas

  • Materials Science(all)
  • Metals and Alloys

Cite this

Molten solvent extraction behavior of trivalent La, Sm, Dy, and Yb with tri-n-butyl phosphate into molten paraffin wax at 60°C. / Peng, Bo; Gao, Jinzhang; Fan, Haiyan; Kang, Jingwan; Yang, Wu.

In: Rare Metals, Vol. 21, No. 1, 03.2002, p. 7-11.

Research output: Contribution to journal › Article

Peng, B, Gao, J, Fan, H, Kang, J & Yang, W 2002, 'Molten solvent extraction behavior of trivalent La, Sm, Dy, and Yb with tri-n-butyl phosphate into molten paraffin wax at 60°C', Rare Metals, vol. 21, no. 1, pp. 7-11.
Peng B, Gao J, Fan H, Kang J, Yang W. Molten solvent extraction behavior of trivalent La, Sm, Dy, and Yb with tri-n-butyl phosphate into molten paraffin wax at 60°C. Rare Metals. 2002 Mar;21(1):7-11.
Peng, Bo ; Gao, Jinzhang ; Fan, Haiyan ; Kang, Jingwan ; Yang, Wu. / Molten solvent extraction behavior of trivalent La, Sm, Dy, and Yb with tri-n-butyl phosphate into molten paraffin wax at 60°C. In: Rare Metals. 2002 ; Vol. 21, No. 1. pp. 7-11.
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AB - The extraction behavior of La3+, Sm3+, Dy3+, and Yb3+ in sodium acetate-acetic acid medium was studied with tri-n-buryl phosphate (TBP) at 60°C using paraffin wax as a diluent. The extraction percentage is greater than 85% in the pH range of 6 to 8. The result of slope analysis method indicates that the compositions of the extracted species is found to be La(TBP)(OH)(Ac)2 for La3+ and Yb(TBP)(OH)3 for Yb3+. The effects of extracting time, the concentration of TBP in the organic phase and salts on the extraction efficiency were also discussed.

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