TY - JOUR
T1 - Morphology and Dimension Variations of Copper Sulfide for High-Performance Electrode in Rechargeable Batteries
T2 - A Review
AU - Kalimuldina, Gulnur
AU - Nurpeissova, Arailym
AU - Adylkhanova, Assyl
AU - Adair, Desmond
AU - Taniguchi, Izumi
AU - Bakenov, Zhumabay
N1 - Funding Information:
This work was supported by the research grants 091019CRP2114 “Three-Dimensional All Solid State Rechargeable Batteries” and 240919FD3914 “Self-Charging Rechargeable Lithium-ion Battery” from Nazarbayev University and the research projects AP05133706 “Innovative High-Capacity Anodes Based on Lithium Titanate for a Next Generation of Batteries” and AP08052143 “Development of Wearable Self-Charging Power Unit” from the Ministry of Education and Science of the Republic of Kazakhstan.
Publisher Copyright:
© 2020 American Chemical Society. All rights reserved.
Copyright:
Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020
Y1 - 2020
N2 - Currently, different metal sulfides (NiS, Co9S8, FeS2, and CuS) have been extensively studied as alternative electrodes for rechargeable batteries that can satisfy the performance requirements for more powerful energy supply and storage technologies for various applications and industries. Among them, copper sulfides have gained significant attention as a promising electrode material in rechargeable metal-ion (Li, Mg, Na, and Al) batteries. A wide range of synthesis routes and methods have been implemented in order to prepare various stoichiometry CuxS (1 ≤ x ≤ 2) micro-/nanostructured materials with excellent electrochemical properties. Since the bulk microsized electrode materials have almost reached their performance limits for energy devices, the introduction of nanoscale CuxS composites is now in high demand. This review focuses on the influence of the material morphology and dimensions on their performance in secondary batteries. The structures of CuxS materials from zero-dimensional (0D) to 3D and their preparation are discussed. The primary purpose of this work is to provide an overview of the unique electrochemical and physical properties of particular structure and dimensionality which can promote these materials' application in the energy storage field. Along with this, this work summarizes the information on various synthesis strategies and how they can manage the morphologies of CuxS micro-/nanocomposites. In the current fast technologically advancing society, the development of the most economically profitable and efficient synthesis routes is especially encouraged and required, and this aspect is also commented on in this review.
AB - Currently, different metal sulfides (NiS, Co9S8, FeS2, and CuS) have been extensively studied as alternative electrodes for rechargeable batteries that can satisfy the performance requirements for more powerful energy supply and storage technologies for various applications and industries. Among them, copper sulfides have gained significant attention as a promising electrode material in rechargeable metal-ion (Li, Mg, Na, and Al) batteries. A wide range of synthesis routes and methods have been implemented in order to prepare various stoichiometry CuxS (1 ≤ x ≤ 2) micro-/nanostructured materials with excellent electrochemical properties. Since the bulk microsized electrode materials have almost reached their performance limits for energy devices, the introduction of nanoscale CuxS composites is now in high demand. This review focuses on the influence of the material morphology and dimensions on their performance in secondary batteries. The structures of CuxS materials from zero-dimensional (0D) to 3D and their preparation are discussed. The primary purpose of this work is to provide an overview of the unique electrochemical and physical properties of particular structure and dimensionality which can promote these materials' application in the energy storage field. Along with this, this work summarizes the information on various synthesis strategies and how they can manage the morphologies of CuxS micro-/nanocomposites. In the current fast technologically advancing society, the development of the most economically profitable and efficient synthesis routes is especially encouraged and required, and this aspect is also commented on in this review.
KW - 0D copper sulfide
KW - 1D copper sulfide
KW - 2D copper sulfide
KW - 3D copper sulfide
KW - copper sulfide
KW - dimensionality
KW - lithium-ion battery
KW - metal sulfide
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U2 - 10.1021/acsaem.0c01686
DO - 10.1021/acsaem.0c01686
M3 - Review article
AN - SCOPUS:85096675994
VL - 3
SP - 11480
EP - 11499
JO - ACS Applied Energy Materials
JF - ACS Applied Energy Materials
SN - 2574-0962
IS - 12
ER -