Morphology and local electrical properties of PTB7

PC71BM blends

Alexander Alekseev, Gordon J. Hedley, Alaa Al-Afeef, Oleg A. Ageev, Ifor D W Samuel

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The power conversion efficiency of single layer organic solar cells can approach 10% with blends such as the polymer PTB7 and the fullerene derivative PC71BM. Here the detailed structure of PTB7:PC71BM blends deposited with and without addition of diiodooctane is studied by transmission electron microscopy and scanning probe microscopy. The details of bulk structure, such as the thickness of the layer covering fullerene domains and the grain structure of the film are examined. We find that fullerene-rich domains can be near the surface of the film or buried deeper, near the substrate. The local electrical properties of these blends are studied by conductive atomic force microscopy for different configurations of electrodes. Different power conversion efficiencies of blends with and without diiodooctane are explained in terms of local photoconductive properties.

Original languageEnglish
Pages (from-to)8706-8714
Number of pages9
JournalJournal of Materials Chemistry A
Volume3
Issue number16
DOIs
Publication statusPublished - Apr 28 2015
Externally publishedYes

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Fullerenes
Electric properties
Conversion efficiency
Scanning probe microscopy
Crystal microstructure
Atomic force microscopy
Polymers
Transmission electron microscopy
Derivatives
Electrodes
Substrates

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Cite this

Morphology and local electrical properties of PTB7 : PC71BM blends. / Alekseev, Alexander; Hedley, Gordon J.; Al-Afeef, Alaa; Ageev, Oleg A.; Samuel, Ifor D W.

In: Journal of Materials Chemistry A, Vol. 3, No. 16, 28.04.2015, p. 8706-8714.

Research output: Contribution to journalArticle

Alekseev, Alexander ; Hedley, Gordon J. ; Al-Afeef, Alaa ; Ageev, Oleg A. ; Samuel, Ifor D W. / Morphology and local electrical properties of PTB7 : PC71BM blends. In: Journal of Materials Chemistry A. 2015 ; Vol. 3, No. 16. pp. 8706-8714.
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