Nanocatalysts for Suzuki cross-coupling reactions

Aziz Fihri, Mohamed Bouhrara, Bijan Nekoueishahraki, Jean Marie Basset, Vivek Polshettiwar

Research output: Contribution to journalArticle

509 Citations (Scopus)

Abstract

This critical review deals with the applications of nanocatalysts in Suzuki coupling reactions, a field that has attracted immense interest in the chemical, materials and industrial communities. We intend to present a broad overview of nanocatalysts for Suzuki coupling reactions with an emphasis on their performance, stability and reusability. We begin the review with a discussion on the importance of Suzuki cross-coupling reactions, and we then discuss fundamental aspects of nanocatalysis, such as the effects of catalyst size and shape. Next, we turn to the core focus of this review: the synthesis, advantages and disadvantages of nanocatalysts for Suzuki coupling reactions. We begin with various nanocatalysts that are based on conventional supports, such as high surface silica, carbon nanotubes, polymers, metal oxides and double hydroxides. Thereafter, we reviewed nanocatalysts based on non-conventional supports, such as dendrimers, cyclodextrin and magnetic nanomaterials. Finally, we discuss nanocatalyst systems that are based on non-conventional media, i.e., fluorous media and ionic liquids, for use in Suzuki reactions. At the end of this review, we summarise the significance of nanocatalysts, their impacts on conventional catalysis and perspectives for further developments of Suzuki cross-coupling reactions (131 references).

Original languageEnglish
Pages (from-to)5181-5203
Number of pages23
JournalChemical Society Reviews
Volume40
Issue number10
DOIs
Publication statusPublished - Oct 2011
Externally publishedYes

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Hydroxides
Dendrimers
Ionic Liquids
Carbon Nanotubes
Cyclodextrins
Reusability
Nanostructured materials
Silicon Dioxide
Oxides
Catalysis
Polymers
Metals
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Fihri, A., Bouhrara, M., Nekoueishahraki, B., Basset, J. M., & Polshettiwar, V. (2011). Nanocatalysts for Suzuki cross-coupling reactions. Chemical Society Reviews, 40(10), 5181-5203. https://doi.org/10.1039/c1cs15079k

Nanocatalysts for Suzuki cross-coupling reactions. / Fihri, Aziz; Bouhrara, Mohamed; Nekoueishahraki, Bijan; Basset, Jean Marie; Polshettiwar, Vivek.

In: Chemical Society Reviews, Vol. 40, No. 10, 10.2011, p. 5181-5203.

Research output: Contribution to journalArticle

Fihri, A, Bouhrara, M, Nekoueishahraki, B, Basset, JM & Polshettiwar, V 2011, 'Nanocatalysts for Suzuki cross-coupling reactions', Chemical Society Reviews, vol. 40, no. 10, pp. 5181-5203. https://doi.org/10.1039/c1cs15079k
Fihri A, Bouhrara M, Nekoueishahraki B, Basset JM, Polshettiwar V. Nanocatalysts for Suzuki cross-coupling reactions. Chemical Society Reviews. 2011 Oct;40(10):5181-5203. https://doi.org/10.1039/c1cs15079k
Fihri, Aziz ; Bouhrara, Mohamed ; Nekoueishahraki, Bijan ; Basset, Jean Marie ; Polshettiwar, Vivek. / Nanocatalysts for Suzuki cross-coupling reactions. In: Chemical Society Reviews. 2011 ; Vol. 40, No. 10. pp. 5181-5203.
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