Nanocomposites based on multicomponent polymer matrix and artificial diamond nanofiller

L. V. Karabanova; V. A. Bershtein; A. W. Lloyd; S. V. Mikhalovsky

Nanocomposites based on multicomponent polymer matrix and artificial diamond nanofiller

L. V. Karabanova, V. A. Bershtein, A. W. Lloyd, S. V. Mikhalovsky

School of Engineering and Digital Sciences

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

1 Citation (Scopus)

Abstract

Nanocomposites based on Polyurethane/Poly(2-hydroxyethyl methacrylate) multicomponent polymer matrix and atrificial diamond nanofiller were created and the thermodynamic miscibility, dynamic mechanical, physico-mechanical properties and segmental motions have been investigated. The free energy of interaction values between the polymer components and nanofiller, calculated based on vapour sorption results, were negative and the thermodynamic affinity of PU network to the nanodiamonds is more powerful in compare with PHEMA. Dynamic mechanical analysis have demonstrated the essential changes in nanocomposites behaviour especially in the temperature range of PU glass transition. The creep rate spectroscopy have shown the suppression of segmental motion of PU and PHEMA in the nanocomposites, the maximal effect have been obtained for samples containing 0.25% of nanofiller. Introduction just of 0.25% of nanodiamond filler into the multicomponent polymer matrix resulted in the significant growth in stress at break and in Young's modulus.

Original language	English
Title of host publication	ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials
Publisher	European Conference on Composite Materials, ECCM
ISBN (Print)	9788888785332
Publication status	Published - Jan 1 2012
Event	15th European Conference on Composite Materials: Composites at Venice, ECCM 2012 - Venice, Italy Duration: Jun 24 2012 → Jun 28 2012

Publication series

Name	ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials

Other

Other	15th European Conference on Composite Materials: Composites at Venice, ECCM 2012
Country	Italy
City	Venice
Period	6/24/12 → 6/28/12

Keywords

Diamond nanofiller
Dynamic mechanical properties
Nanocomposites
Thermodynamic of interactions

ASJC Scopus subject areas

Ceramics and Composites

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Cite this

Karabanova, L. V., Bershtein, V. A., Lloyd, A. W., & Mikhalovsky, S. V. (2012). Nanocomposites based on multicomponent polymer matrix and artificial diamond nanofiller. In ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials (ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials). European Conference on Composite Materials, ECCM.

Nanocomposites based on multicomponent polymer matrix and artificial diamond nanofiller. / Karabanova, L. V.; Bershtein, V. A.; Lloyd, A. W.; Mikhalovsky, S. V.

ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials. European Conference on Composite Materials, ECCM, 2012. (ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Karabanova, LV, Bershtein, VA, Lloyd, AW & Mikhalovsky, SV 2012, Nanocomposites based on multicomponent polymer matrix and artificial diamond nanofiller. in ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials. ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials, European Conference on Composite Materials, ECCM, 15th European Conference on Composite Materials: Composites at Venice, ECCM 2012, Venice, Italy, 6/24/12.

Karabanova LV, Bershtein VA, Lloyd AW, Mikhalovsky SV. Nanocomposites based on multicomponent polymer matrix and artificial diamond nanofiller. In ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials. European Conference on Composite Materials, ECCM. 2012. (ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials).

Karabanova, L. V. ; Bershtein, V. A. ; Lloyd, A. W. ; Mikhalovsky, S. V. / Nanocomposites based on multicomponent polymer matrix and artificial diamond nanofiller. ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials. European Conference on Composite Materials, ECCM, 2012. (ECCM 2012 - Composites at Venice, Proceedings of the 15th European Conference on Composite Materials).

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AU - Karabanova, L. V.

AU - Bershtein, V. A.

AU - Lloyd, A. W.

AU - Mikhalovsky, S. V.

PY - 2012/1/1

Y1 - 2012/1/1

N2 - Nanocomposites based on Polyurethane/Poly(2-hydroxyethyl methacrylate) multicomponent polymer matrix and atrificial diamond nanofiller were created and the thermodynamic miscibility, dynamic mechanical, physico-mechanical properties and segmental motions have been investigated. The free energy of interaction values between the polymer components and nanofiller, calculated based on vapour sorption results, were negative and the thermodynamic affinity of PU network to the nanodiamonds is more powerful in compare with PHEMA. Dynamic mechanical analysis have demonstrated the essential changes in nanocomposites behaviour especially in the temperature range of PU glass transition. The creep rate spectroscopy have shown the suppression of segmental motion of PU and PHEMA in the nanocomposites, the maximal effect have been obtained for samples containing 0.25% of nanofiller. Introduction just of 0.25% of nanodiamond filler into the multicomponent polymer matrix resulted in the significant growth in stress at break and in Young's modulus.

AB - Nanocomposites based on Polyurethane/Poly(2-hydroxyethyl methacrylate) multicomponent polymer matrix and atrificial diamond nanofiller were created and the thermodynamic miscibility, dynamic mechanical, physico-mechanical properties and segmental motions have been investigated. The free energy of interaction values between the polymer components and nanofiller, calculated based on vapour sorption results, were negative and the thermodynamic affinity of PU network to the nanodiamonds is more powerful in compare with PHEMA. Dynamic mechanical analysis have demonstrated the essential changes in nanocomposites behaviour especially in the temperature range of PU glass transition. The creep rate spectroscopy have shown the suppression of segmental motion of PU and PHEMA in the nanocomposites, the maximal effect have been obtained for samples containing 0.25% of nanofiller. Introduction just of 0.25% of nanodiamond filler into the multicomponent polymer matrix resulted in the significant growth in stress at break and in Young's modulus.

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KW - Dynamic mechanical properties

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KW - Thermodynamic of interactions

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