Na4Mn9O18/Carbon Nanotube Composite as a High Electrochemical Performance Material for Aqueous Sodium-Ion Batteries

Fuxing Yin; Zhengjun Liu; Shuang Yang; Zhenzhen Shan; Yan Zhao; Yuting Feng; Chengwei Zhang; Zhumabay Bakenov

doi:10.1186/s11671-017-2340-1

Na₄Mn₉O₁₈/Carbon Nanotube Composite as a High Electrochemical Performance Material for Aqueous Sodium-Ion Batteries

Fuxing Yin, Zhengjun Liu, Shuang Yang, Zhenzhen Shan, Yan Zhao, Yuting Feng, Chengwei Zhang, Zhumabay Bakenov

School of Engineering and Digital Sciences

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The aqueous sodium-ion battery (ASIB) is one of the promising new energy storage systems owing to the abundant resources of sodium as well as efficiency and safety of electrolyte. Herein, we report an ASIB system with Na₄Mn₉O₁₈/carbon nanotube (NMO/CNT) as cathode, metal Zn as anode and a novel Na⁺/Zn²⁺ mixed ion as electrolyte. The NMO/CNT with microspherical structure is prepared by a simple spray-drying method. The prepared battery delivers a high reversible specific capacity and stable cyclability. Furthermore, the battery displays a stable reversible discharge capacity of 53.2 mAh g⁻¹ even at a high current rate of 4 C after 150 cycles. Our results confirm that the NMO/CNT composite is a promising electrode cathode material for ASIBs.

Original language	English
Article number	569
Journal	Nanoscale Research Letters
Volume	12
DOIs	https://doi.org/10.1186/s11671-017-2340-1
Publication status	Published - 2017

Keywords

Aqueous sodium-ion battery
Cathode
Energy storage and conversion
NaMnO/carbon nanotube

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics

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title = "Na4Mn9O18/Carbon Nanotube Composite as a High Electrochemical Performance Material for Aqueous Sodium-Ion Batteries",

abstract = "The aqueous sodium-ion battery (ASIB) is one of the promising new energy storage systems owing to the abundant resources of sodium as well as efficiency and safety of electrolyte. Herein, we report an ASIB system with Na4Mn9O18/carbon nanotube (NMO/CNT) as cathode, metal Zn as anode and a novel Na+/Zn2+ mixed ion as electrolyte. The NMO/CNT with microspherical structure is prepared by a simple spray-drying method. The prepared battery delivers a high reversible specific capacity and stable cyclability. Furthermore, the battery displays a stable reversible discharge capacity of 53.2 mAh g−1 even at a high current rate of 4 C after 150 cycles. Our results confirm that the NMO/CNT composite is a promising electrode cathode material for ASIBs.",

keywords = "Aqueous sodium-ion battery, Cathode, Energy storage and conversion, NaMnO/carbon nanotube",

author = "Fuxing Yin and Zhengjun Liu and Shuang Yang and Zhenzhen Shan and Yan Zhao and Yuting Feng and Chengwei Zhang and Zhumabay Bakenov",

year = "2017",

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T1 - Na4Mn9O18/Carbon Nanotube Composite as a High Electrochemical Performance Material for Aqueous Sodium-Ion Batteries

AU - Yin, Fuxing

AU - Liu, Zhengjun

AU - Yang, Shuang

AU - Shan, Zhenzhen

AU - Zhao, Yan

AU - Feng, Yuting

AU - Zhang, Chengwei

AU - Bakenov, Zhumabay

PY - 2017

Y1 - 2017

N2 - The aqueous sodium-ion battery (ASIB) is one of the promising new energy storage systems owing to the abundant resources of sodium as well as efficiency and safety of electrolyte. Herein, we report an ASIB system with Na4Mn9O18/carbon nanotube (NMO/CNT) as cathode, metal Zn as anode and a novel Na+/Zn2+ mixed ion as electrolyte. The NMO/CNT with microspherical structure is prepared by a simple spray-drying method. The prepared battery delivers a high reversible specific capacity and stable cyclability. Furthermore, the battery displays a stable reversible discharge capacity of 53.2 mAh g−1 even at a high current rate of 4 C after 150 cycles. Our results confirm that the NMO/CNT composite is a promising electrode cathode material for ASIBs.

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KW - Aqueous sodium-ion battery

KW - Cathode

KW - Energy storage and conversion

KW - NaMnO/carbon nanotube

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