Nickel Hexacyanoferrate Nanoparticles as a Low Cost Cathode Material for Lithium-Ion Batteries

Marzhana Omarova; Aibolat Koishybay; Nulati Yesibolati; Almagul Mentbayeva; Nurzhan Umirov; Kairat Ismailov; Desmond Adair; Moulay Rachid Babaa; Indira Kurmanbayeva; Zhumabay Bakenov

doi:10.1016/j.electacta.2015.10.031

Nickel Hexacyanoferrate Nanoparticles as a Low Cost Cathode Material for Lithium-Ion Batteries

Marzhana Omarova, Aibolat Koishybay, Nulati Yesibolati, Almagul Mentbayeva, Nurzhan Umirov, Kairat Ismailov, Desmond Adair, Moulay Rachid Babaa, Indira Kurmanbayeva, Zhumabay Bakenov

Research output: Contribution to journal › Article

27 Citations (Scopus)

Abstract

Potassium nickel hexacyanoferrate KNi[Fe(CN)₆] (NiHCF) was synthesized by a simple co-precipitation method and investigated as a cathode material for lithium-ion batteries. The X-ray diffraction and transmission electron microscopy studies revealed the formation of pure phase of agglomerated NiHCF nanoparticles of about 20-50 nm in size. The material exhibited stable cycling performance as a cathode in a lithium half-cell within a wide range of current densities, and a working potential around 3.3 V vs. Li⁺/Li. The lithium ion diffusion coefficient in this system was determined to be in a range of 10^-9 to 10^-8 cm² s^-1, which is within the values for the cathode materials for lithium-ion batteries with high rate capability. Considering promising electrochemical performance and attractive lithium-ion diffusion properties of this material along with its economical benefits and simplified preparation, NiHCF could be considered as a very promising cathode for large scale lithium-ion batteries.

Original language	English
Pages (from-to)	58-63
Number of pages	6
Journal	Electrochimica Acta
Volume	184
DOIs	https://doi.org/10.1016/j.electacta.2015.10.031
Publication status	Published - Dec 1 2015

Keywords

Galvanostatic Intermittent Titration Technique
Lithium Diffusion Coefficient
Lithium-ion Battery
Nickel Hexacyanoferrate Cathode

ASJC Scopus subject areas

Electrochemistry
Chemical Engineering(all)

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Omarova, M., Koishybay, A., Yesibolati, N., Mentbayeva, A., Umirov, N., Ismailov, K., Adair, D., Babaa, M. R., Kurmanbayeva, I., & Bakenov, Z. (2015). Nickel Hexacyanoferrate Nanoparticles as a Low Cost Cathode Material for Lithium-Ion Batteries. Electrochimica Acta, 184, 58-63. https://doi.org/10.1016/j.electacta.2015.10.031

Nickel Hexacyanoferrate Nanoparticles as a Low Cost Cathode Material for Lithium-Ion Batteries. / Omarova, Marzhana; Koishybay, Aibolat; Yesibolati, Nulati; Mentbayeva, Almagul ; Umirov, Nurzhan ; Ismailov, Kairat ; Adair, Desmond; Babaa, Moulay Rachid; Kurmanbayeva, Indira ; Bakenov, Zhumabay.

In: Electrochimica Acta, Vol. 184, 01.12.2015, p. 58-63.

Research output: Contribution to journal › Article

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abstract = "Potassium nickel hexacyanoferrate KNi[Fe(CN)6] (NiHCF) was synthesized by a simple co-precipitation method and investigated as a cathode material for lithium-ion batteries. The X-ray diffraction and transmission electron microscopy studies revealed the formation of pure phase of agglomerated NiHCF nanoparticles of about 20-50 nm in size. The material exhibited stable cycling performance as a cathode in a lithium half-cell within a wide range of current densities, and a working potential around 3.3 V vs. Li+/Li. The lithium ion diffusion coefficient in this system was determined to be in a range of 10-9 to 10-8 cm2 s-1, which is within the values for the cathode materials for lithium-ion batteries with high rate capability. Considering promising electrochemical performance and attractive lithium-ion diffusion properties of this material along with its economical benefits and simplified preparation, NiHCF could be considered as a very promising cathode for large scale lithium-ion batteries.",

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