TY - JOUR
T1 - Nickel Hexacyanoferrate Nanoparticles as a Low Cost Cathode Material for Lithium-Ion Batteries
AU - Omarova, Marzhana
AU - Koishybay, Aibolat
AU - Yesibolati, Nulati
AU - Mentbayeva, Almagul
AU - Umirov, Nurzhan
AU - Ismailov, Kairat
AU - Adair, Desmond
AU - Babaa, Moulay Rachid
AU - Kurmanbayeva, Indira
AU - Bakenov, Zhumabay
N1 - Funding Information:
This research was supported by the Research Grant from Nazarbayev University, by a Subproject # 157-2013 funded under the Technology Commercialization Project by the World Bank and the Government of the Republic of Kazakhstan and by a research grant 5097/GF4 from the Ministry of Education and Science of Kazakhstan. The authors acknowledge the PI Nazarbayev Research and Innovation System (Dr. K. Baigarin, Mr. M. Moldabek, Mr. Y. Iskakov) for providing administrative support for this work.
Publisher Copyright:
� 2015 Elsevier Ltd.
PY - 2015/12/1
Y1 - 2015/12/1
N2 - Potassium nickel hexacyanoferrate KNi[Fe(CN)6] (NiHCF) was synthesized by a simple co-precipitation method and investigated as a cathode material for lithium-ion batteries. The X-ray diffraction and transmission electron microscopy studies revealed the formation of pure phase of agglomerated NiHCF nanoparticles of about 20-50 nm in size. The material exhibited stable cycling performance as a cathode in a lithium half-cell within a wide range of current densities, and a working potential around 3.3 V vs. Li+/Li. The lithium ion diffusion coefficient in this system was determined to be in a range of 10-9 to 10-8 cm2 s-1, which is within the values for the cathode materials for lithium-ion batteries with high rate capability. Considering promising electrochemical performance and attractive lithium-ion diffusion properties of this material along with its economical benefits and simplified preparation, NiHCF could be considered as a very promising cathode for large scale lithium-ion batteries.
AB - Potassium nickel hexacyanoferrate KNi[Fe(CN)6] (NiHCF) was synthesized by a simple co-precipitation method and investigated as a cathode material for lithium-ion batteries. The X-ray diffraction and transmission electron microscopy studies revealed the formation of pure phase of agglomerated NiHCF nanoparticles of about 20-50 nm in size. The material exhibited stable cycling performance as a cathode in a lithium half-cell within a wide range of current densities, and a working potential around 3.3 V vs. Li+/Li. The lithium ion diffusion coefficient in this system was determined to be in a range of 10-9 to 10-8 cm2 s-1, which is within the values for the cathode materials for lithium-ion batteries with high rate capability. Considering promising electrochemical performance and attractive lithium-ion diffusion properties of this material along with its economical benefits and simplified preparation, NiHCF could be considered as a very promising cathode for large scale lithium-ion batteries.
KW - Galvanostatic Intermittent Titration Technique
KW - Lithium Diffusion Coefficient
KW - Lithium-ion Battery
KW - Nickel Hexacyanoferrate Cathode
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U2 - 10.1016/j.electacta.2015.10.031
DO - 10.1016/j.electacta.2015.10.031
M3 - Article
AN - SCOPUS:84944732649
VL - 184
SP - 58
EP - 63
JO - Electrochimica Acta
JF - Electrochimica Acta
SN - 0013-4686
ER -