Quantifying the Nongeminate Recombination Dynamics in Nonfullerene Bulk Heterojunction Organic Solar Cells

Joachim Vollbrecht, Viktor V. Brus, Seo Jin Ko, Jaewon Lee, Akchheta Karki, David Xi Cao, Kilwon Cho, Guillermo C. Bazan, Thuc Quyen Nguyen

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

In this study, a comprehensive analytical model to quantify the total nongeminate recombination losses, originating from bimolecular as well as bulk and surface trap-assisted recombination mechanisms in nonfullerene-based bulk heterojunction organic solar cells is developed. This proposed model is successfully employed to obtain the different contributions to the recombination current of the investigated solar cells under different illumination intensities. Additionally, the model quantitatively describes the experimentally measured open-circuit voltage versus light intensity dependence. Most importantly, it is possible to calculate the experimental results with the same fitting parameter values from the presented model. The validity of this model is also proven by a combination of other independent, steady-state, and transient experimental techniques. This new powerful analytical tool will enable researchers in the photovoltaic community to take into account the synergetic contribution from all relevant types of nongeminate recombination losses in different optoelectronic systems and target their analysis of recombination dynamics at any operating voltage.

Original languageEnglish
Article number1901438
JournalAdvanced Energy Materials
Volume9
Issue number32
DOIs
Publication statusPublished - 2019
Externally publishedYes

Keywords

  • impedance spectroscopy
  • nonfullerene acceptors
  • nongeminate recombination
  • organic bulk heterojunction solar cells

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)

Fingerprint Dive into the research topics of 'Quantifying the Nongeminate Recombination Dynamics in Nonfullerene Bulk Heterojunction Organic Solar Cells'. Together they form a unique fingerprint.

Cite this