Soluble high-molecular-mass poly(ethylene oxide)s via self-organization

Stefan Schmatloch, Antje M.J. Van Den Berg, Alexander S. Alexeev, Harald Hofmeier, Ulrich S. Schubert

Research output: Contribution to journalArticlepeer-review

117 Citations (Scopus)

Abstract

High-molecular-weight poly(ethylene oxide)s are utilized for a wide variety of different applications. Here we present a new strategy for the large-scale synthesis of modified metallosupra-molecular poly(ethylene oxide)s on the basis of the metal-induced self-assembly of bis(2,2′:6′,2″-terpyrid-4′-yl)-poly (ethylene oxide)179. The influence of different metal ions (cadmium(II), copper(II), cobalt(II), nickel(II), iron(II)) on the degree of polymerization and the resulting molecular weight were evaluated. Elaborated reaction conditions allow easy access to high-molecular-weight iron(II) coordination polymers via self-organization. The polymers were characterized in detail utilizing 1H NMR, UV/vis spectroscopy, MALDI-TOF-MS, and viscosity measurements. The molecular weight was estimated on the basis of concentration-dependent viscosity measurements to about 80 000 g/mol. Furthermore, the morphology of the utilized telechelic bis(2,2′:6′,2″-terpyrid-4′-yl)-poly(ethylene oxide)179 and the corresponding coordination polymer was investigated using atomic force microscopy. In particular, the influence of complex formation on the morphology was investigated.

Original languageEnglish
Pages (from-to)9943-9949
Number of pages7
JournalMacromolecules
Volume36
Issue number26
DOIs
Publication statusPublished - Dec 30 2003

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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