Studies on Functionalization of N,O-Chelated Isoquinoline-Enol Boron Complexes

Jianjun Huang, Yingchun Wang, Kristof Van Hecke, Olga P. Pereshivko, Vsevolod A. Peshkov

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

A small set of N,O-chelated isoquinoline-enol boron complexes featuring an aryl bromide functionality was prepared and employed in palladium-catalyzed Suzuki couplings with arylboronic acids and bis(pinacolato)diboron. This allowed to obtain two new series of functionalized N,O-chelated boron complexes and a novel type of bis-fluorophore hybrid. The optical properties of all obtained complexes were assessed in solid state and in dichloromethane solution.

Original languageEnglish
Pages (from-to)2490-2497
Number of pages8
JournalEuropean Journal of Organic Chemistry
Volume2019
Issue number14
DOIs
Publication statusPublished - Apr 16 2019

Fingerprint

Boron
boron
Fluorophores
Methylene Chloride
Palladium
Bromides
palladium
bromides
Optical properties
solid state
optical properties
acids
Acids
isoquinoline
bis(pinacolato)diboron

Keywords

  • Boron
  • Functionalization
  • Iuminescence
  • Solid-state emission
  • Substituent effects

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Studies on Functionalization of N,O-Chelated Isoquinoline-Enol Boron Complexes. / Huang, Jianjun; Wang, Yingchun; Van Hecke, Kristof; Pereshivko, Olga P.; Peshkov, Vsevolod A.

In: European Journal of Organic Chemistry, Vol. 2019, No. 14, 16.04.2019, p. 2490-2497.

Research output: Contribution to journalArticle

Huang, Jianjun ; Wang, Yingchun ; Van Hecke, Kristof ; Pereshivko, Olga P. ; Peshkov, Vsevolod A. / Studies on Functionalization of N,O-Chelated Isoquinoline-Enol Boron Complexes. In: European Journal of Organic Chemistry. 2019 ; Vol. 2019, No. 14. pp. 2490-2497.
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