Abstract
A small set of N,O-chelated isoquinoline-enol boron complexes featuring an aryl bromide functionality was prepared and employed in palladium-catalyzed Suzuki couplings with arylboronic acids and bis(pinacolato)diboron. This allowed to obtain two new series of functionalized N,O-chelated boron complexes and a novel type of bis-fluorophore hybrid. The optical properties of all obtained complexes were assessed in solid state and in dichloromethane solution.
| Original language | English |
|---|---|
| Pages (from-to) | 2490-2497 |
| Number of pages | 8 |
| Journal | European Journal of Organic Chemistry |
| Volume | 2019 |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - Apr 16 2019 |
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Keywords
- Boron
- Functionalization
- Iuminescence
- Solid-state emission
- Substituent effects
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
Cite this
Studies on Functionalization of N,O-Chelated Isoquinoline-Enol Boron Complexes. / Huang, Jianjun; Wang, Yingchun; Van Hecke, Kristof; Pereshivko, Olga P.; Peshkov, Vsevolod A.
In: European Journal of Organic Chemistry, Vol. 2019, No. 14, 16.04.2019, p. 2490-2497.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Studies on Functionalization of N,O-Chelated Isoquinoline-Enol Boron Complexes
AU - Huang, Jianjun
AU - Wang, Yingchun
AU - Van Hecke, Kristof
AU - Pereshivko, Olga P.
AU - Peshkov, Vsevolod A.
PY - 2019/4/16
Y1 - 2019/4/16
N2 - A small set of N,O-chelated isoquinoline-enol boron complexes featuring an aryl bromide functionality was prepared and employed in palladium-catalyzed Suzuki couplings with arylboronic acids and bis(pinacolato)diboron. This allowed to obtain two new series of functionalized N,O-chelated boron complexes and a novel type of bis-fluorophore hybrid. The optical properties of all obtained complexes were assessed in solid state and in dichloromethane solution.
AB - A small set of N,O-chelated isoquinoline-enol boron complexes featuring an aryl bromide functionality was prepared and employed in palladium-catalyzed Suzuki couplings with arylboronic acids and bis(pinacolato)diboron. This allowed to obtain two new series of functionalized N,O-chelated boron complexes and a novel type of bis-fluorophore hybrid. The optical properties of all obtained complexes were assessed in solid state and in dichloromethane solution.
KW - Boron
KW - Functionalization
KW - Iuminescence
KW - Solid-state emission
KW - Substituent effects
UR - http://www.scopus.com/inward/record.url?scp=85063566998&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85063566998&partnerID=8YFLogxK
U2 - 10.1002/ejoc.201801872
DO - 10.1002/ejoc.201801872
M3 - Article
VL - 2019
SP - 2490
EP - 2497
JO - Annalen der Pharmacie
JF - Annalen der Pharmacie
SN - 0075-4617
IS - 14
ER -