Abstract
A small set of N,O-chelated isoquinoline-enol boron complexes featuring an aryl bromide functionality was prepared and employed in palladium-catalyzed Suzuki couplings with arylboronic acids and bis(pinacolato)diboron. This allowed to obtain two new series of functionalized N,O-chelated boron complexes and a novel type of bis-fluorophore hybrid. The optical properties of all obtained complexes were assessed in solid state and in dichloromethane solution.
Original language | English |
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Pages (from-to) | 2490-2497 |
Number of pages | 8 |
Journal | European Journal of Organic Chemistry |
Volume | 2019 |
Issue number | 14 |
DOIs | |
Publication status | Published - Apr 16 2019 |
Keywords
- Boron
- Functionalization
- Iuminescence
- Solid-state emission
- Substituent effects
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry