Abstract
A small set of N,O-chelated isoquinoline-enol boron complexes featuring an aryl bromide functionality was prepared and employed in palladium-catalyzed Suzuki couplings with arylboronic acids and bis(pinacolato)diboron. This allowed to obtain two new series of functionalized N,O-chelated boron complexes and a novel type of bis-fluorophore hybrid. The optical properties of all obtained complexes were assessed in solid state and in dichloromethane solution.
| Original language | English |
|---|---|
| Pages (from-to) | 2490-2497 |
| Number of pages | 8 |
| Journal | European Journal of Organic Chemistry |
| Volume | 2019 |
| Issue number | 14 |
| DOIs | |
| Publication status | Published - Apr 16 2019 |
Keywords
- Boron
- Functionalization
- Iuminescence
- Solid-state emission
- Substituent effects
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
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Cite this
Huang, J., Wang, Y., Van Hecke, K., Pereshivko, O. P., & Peshkov, V. A. (2019). Studies on Functionalization of N,O-Chelated Isoquinoline-Enol Boron Complexes. European Journal of Organic Chemistry, 2019(14), 2490-2497. https://doi.org/10.1002/ejoc.201801872