Studies on Functionalization of N,O-Chelated Isoquinoline-Enol Boron Complexes

Jianjun Huang, Yingchun Wang, Kristof Van Hecke, Olga P. Pereshivko, Vsevolod A. Peshkov

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

A small set of N,O-chelated isoquinoline-enol boron complexes featuring an aryl bromide functionality was prepared and employed in palladium-catalyzed Suzuki couplings with arylboronic acids and bis(pinacolato)diboron. This allowed to obtain two new series of functionalized N,O-chelated boron complexes and a novel type of bis-fluorophore hybrid. The optical properties of all obtained complexes were assessed in solid state and in dichloromethane solution.

Original languageEnglish
Pages (from-to)2490-2497
Number of pages8
JournalEuropean Journal of Organic Chemistry
Volume2019
Issue number14
DOIs
Publication statusPublished - Apr 16 2019

Keywords

  • Boron
  • Functionalization
  • Iuminescence
  • Solid-state emission
  • Substituent effects

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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