Synthesis and heavy‐metal sorption studies of n,n‐dimethylacrylamide‐based hydrogels

Ayatzhan Akhmetzhan; Nurgeldi Abeu; Sotirios Nik Longinos; Ayezkhan Tashenov; Nurbala Myrzakhmetova; Nurgul Amangeldi; Zhanar Kuanyshova; Zhanar Ospanova; Zhexenbek Toktarbay

doi:10.3390/polym13183084

Synthesis and heavy‐metal sorption studies of n,n‐dimethylacrylamide‐based hydrogels

Ayatzhan Akhmetzhan, Nurgeldi Abeu, Sotirios Nik Longinos, Ayezkhan Tashenov, Nurbala Myrzakhmetova, Nurgul Amangeldi, Zhanar Kuanyshova, Zhanar Ospanova, Zhexenbek Toktarbay

School of Mining and Geosciences

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

In this work, a hydrogel system was produced via radical polymerization of N,N‐dimethylacrylamide and 2‐acrylamido‐2‐methylpropanesulfonic acid in the presence of N,N‐methylenebis‐acrylamide as a crosslinker and ammonium persulfate as an initiator. Parameters that impact the conversion of copolymerization (such as initial concentration of monomers, temperature, initiator dose, and time) were studied. The swelling degree of the hydrogel was investigated with the addition of a crosslinker and initiator at different pH levels. A hydrogel with high conversion and high swelling degree was selected to investigate their ability for adsorption of Pb(II) ions from solutions. Adsorption behavior of Pb(II) ions in a hydrogel was examined as a function of reaction time and concentration of lead ions from a solution of Pb(II) ions.

Original language	English
Article number	3084
Journal	Polymers
Volume	13
Issue number	18
DOIs	https://doi.org/10.3390/polym13183084
Publication status	Published - Sept 2021

Keywords

AMPS
Crosslinker
DMAA
Hydrogel
Metal‐ion adsorption
Swelling ratio

ASJC Scopus subject areas

General Chemistry
Polymers and Plastics

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10.3390/polym13183084

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title = "Synthesis and heavy‐metal sorption studies of n,n‐dimethylacrylamide‐based hydrogels",

abstract = "In this work, a hydrogel system was produced via radical polymerization of N,N‐dimethylacrylamide and 2‐acrylamido‐2‐methylpropanesulfonic acid in the presence of N,N‐methylenebis‐acrylamide as a crosslinker and ammonium persulfate as an initiator. Parameters that impact the conversion of copolymerization (such as initial concentration of monomers, temperature, initiator dose, and time) were studied. The swelling degree of the hydrogel was investigated with the addition of a crosslinker and initiator at different pH levels. A hydrogel with high conversion and high swelling degree was selected to investigate their ability for adsorption of Pb(II) ions from solutions. Adsorption behavior of Pb(II) ions in a hydrogel was examined as a function of reaction time and concentration of lead ions from a solution of Pb(II) ions.",

keywords = "AMPS, Crosslinker, DMAA, Hydrogel, Metal‐ion adsorption, Swelling ratio",

author = "Ayatzhan Akhmetzhan and Nurgeldi Abeu and Longinos, \{Sotirios Nik\} and Ayezkhan Tashenov and Nurbala Myrzakhmetova and Nurgul Amangeldi and Zhanar Kuanyshova and Zhanar Ospanova and Zhexenbek Toktarbay",

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year = "2021",

month = sep,

doi = "10.3390/polym13183084",

language = "English",

volume = "13",

journal = "Polymers",

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AU - Akhmetzhan, Ayatzhan

AU - Abeu, Nurgeldi

AU - Longinos, Sotirios Nik

AU - Tashenov, Ayezkhan

AU - Myrzakhmetova, Nurbala

AU - Amangeldi, Nurgul

AU - Kuanyshova, Zhanar

AU - Ospanova, Zhanar

AU - Toktarbay, Zhexenbek

PY - 2021/9

Y1 - 2021/9

N2 - In this work, a hydrogel system was produced via radical polymerization of N,N‐dimethylacrylamide and 2‐acrylamido‐2‐methylpropanesulfonic acid in the presence of N,N‐methylenebis‐acrylamide as a crosslinker and ammonium persulfate as an initiator. Parameters that impact the conversion of copolymerization (such as initial concentration of monomers, temperature, initiator dose, and time) were studied. The swelling degree of the hydrogel was investigated with the addition of a crosslinker and initiator at different pH levels. A hydrogel with high conversion and high swelling degree was selected to investigate their ability for adsorption of Pb(II) ions from solutions. Adsorption behavior of Pb(II) ions in a hydrogel was examined as a function of reaction time and concentration of lead ions from a solution of Pb(II) ions.

AB - In this work, a hydrogel system was produced via radical polymerization of N,N‐dimethylacrylamide and 2‐acrylamido‐2‐methylpropanesulfonic acid in the presence of N,N‐methylenebis‐acrylamide as a crosslinker and ammonium persulfate as an initiator. Parameters that impact the conversion of copolymerization (such as initial concentration of monomers, temperature, initiator dose, and time) were studied. The swelling degree of the hydrogel was investigated with the addition of a crosslinker and initiator at different pH levels. A hydrogel with high conversion and high swelling degree was selected to investigate their ability for adsorption of Pb(II) ions from solutions. Adsorption behavior of Pb(II) ions in a hydrogel was examined as a function of reaction time and concentration of lead ions from a solution of Pb(II) ions.

KW - AMPS

KW - Crosslinker

KW - DMAA

KW - Hydrogel

KW - Metal‐ion adsorption

KW - Swelling ratio

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DO - 10.3390/polym13183084

M3 - Article

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SN - 2073-4360

VL - 13

JO - Polymers

JF - Polymers

IS - 18

M1 - 3084

ER -

Synthesis and heavy‐metal sorption studies of n,n‐dimethylacrylamide‐based hydrogels

Abstract

Keywords

ASJC Scopus subject areas

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