Synthesis of the polymerizable room temperature ionic liquid AMPS - TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide

Tingting Weng; Jianwei Guo; Xinming Li; Yingde Cui; Xuejiao Yang; Kun Zhang; Buning Zhang; Guoqiang Yin; Sergey V. Mikhalovsky; Lyuba I. Mikhalovska; Irina N. Savina; Carol A. Howel; Susan R. Sandeman

doi:10.1080/15685551.2013.840480

Synthesis of the polymerizable room temperature ionic liquid AMPS - TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide

Tingting Weng, Jianwei Guo, Xinming Li, Yingde Cui, Xuejiao Yang, Kun Zhang, Buning Zhang, Guoqiang Yin, Sergey V. Mikhalovsky, Lyuba I. Mikhalovska, Irina N. Savina, Carol A. Howel, Susan R. Sandeman

School of Engineering and Digital Sciences

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2- methyl-1-propane sulfonic acid (AMPS) - triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and ¹H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS - TEA was -59.4 °C. Poly(AMPS - TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed.

Original language	English
Pages (from-to)	140-146
Number of pages	7
Journal	Designed Monomers and Polymers
Volume	17
Issue number	2
DOIs	https://doi.org/10.1080/15685551.2013.840480
Publication status	Published - 2014

Keywords

2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS)
Acrylamide
Room temperature ionic liquid (RTIL)
Superabsorbency
Triethylamine (TEA)

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Polymers and Plastics
Materials Chemistry

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Weng, T., Guo, J., Li, X., Cui, Y., Yang, X., Zhang, K., Zhang, B., Yin, G., Mikhalovsky, S. V., Mikhalovska, L. I., Savina, I. N., Howel, C. A., & Sandeman, S. R. (2014). Synthesis of the polymerizable room temperature ionic liquid AMPS - TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide. Designed Monomers and Polymers, 17(2), 140-146. https://doi.org/10.1080/15685551.2013.840480

Synthesis of the polymerizable room temperature ionic liquid AMPS - TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide. / Weng, Tingting; Guo, Jianwei; Li, Xinming; Cui, Yingde; Yang, Xuejiao; Zhang, Kun; Zhang, Buning; Yin, Guoqiang; Mikhalovsky, Sergey V.; Mikhalovska, Lyuba I.; Savina, Irina N.; Howel, Carol A.; Sandeman, Susan R.

In: Designed Monomers and Polymers, Vol. 17, No. 2, 2014, p. 140-146.

Research output: Contribution to journal › Article › peer-review

Weng, T, Guo, J, Li, X, Cui, Y, Yang, X, Zhang, K, Zhang, B, Yin, G, Mikhalovsky, SV, Mikhalovska, LI, Savina, IN, Howel, CA & Sandeman, SR 2014, 'Synthesis of the polymerizable room temperature ionic liquid AMPS - TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide', Designed Monomers and Polymers, vol. 17, no. 2, pp. 140-146. https://doi.org/10.1080/15685551.2013.840480

Weng, Tingting ; Guo, Jianwei ; Li, Xinming ; Cui, Yingde ; Yang, Xuejiao ; Zhang, Kun ; Zhang, Buning ; Yin, Guoqiang ; Mikhalovsky, Sergey V. ; Mikhalovska, Lyuba I. ; Savina, Irina N. ; Howel, Carol A. ; Sandeman, Susan R. / Synthesis of the polymerizable room temperature ionic liquid AMPS - TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide. In: Designed Monomers and Polymers. 2014 ; Vol. 17, No. 2. pp. 140-146.

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title = "Synthesis of the polymerizable room temperature ionic liquid AMPS - TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide",

abstract = "A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2- methyl-1-propane sulfonic acid (AMPS) - triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and 1H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS - TEA was -59.4 °C. Poly(AMPS - TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed.",

keywords = "2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS), Acrylamide, Room temperature ionic liquid (RTIL), Superabsorbency, Triethylamine (TEA)",

author = "Tingting Weng and Jianwei Guo and Xinming Li and Yingde Cui and Xuejiao Yang and Kun Zhang and Buning Zhang and Guoqiang Yin and Mikhalovsky, {Sergey V.} and Mikhalovska, {Lyuba I.} and Savina, {Irina N.} and Howel, {Carol A.} and Sandeman, {Susan R.}",

note = "Funding Information: This work was supported by EU FP7 IRSES project {\textquoteleft}ABREM{\textquoteright} [grant agreement PIRSES-GA-2009-247599]; Dongguan Municipal Science & Technology Planning Project of China [contract grant no. 201110810100327].",

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doi = "10.1080/15685551.2013.840480",

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T1 - Synthesis of the polymerizable room temperature ionic liquid AMPS - TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide

AU - Weng, Tingting

AU - Guo, Jianwei

AU - Li, Xinming

AU - Cui, Yingde

AU - Yang, Xuejiao

AU - Zhang, Kun

AU - Zhang, Buning

AU - Yin, Guoqiang

AU - Mikhalovsky, Sergey V.

AU - Mikhalovska, Lyuba I.

AU - Savina, Irina N.

AU - Howel, Carol A.

AU - Sandeman, Susan R.

N1 - Funding Information: This work was supported by EU FP7 IRSES project ‘ABREM’ [grant agreement PIRSES-GA-2009-247599]; Dongguan Municipal Science & Technology Planning Project of China [contract grant no. 201110810100327].

PY - 2014

Y1 - 2014

N2 - A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2- methyl-1-propane sulfonic acid (AMPS) - triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and 1H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS - TEA was -59.4 °C. Poly(AMPS - TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed.

AB - A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2- methyl-1-propane sulfonic acid (AMPS) - triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and 1H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS - TEA was -59.4 °C. Poly(AMPS - TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed.

KW - 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS)

KW - Acrylamide

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KW - Superabsorbency

KW - Triethylamine (TEA)

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