The effect of coupling and di-anchoring group in the performance of triphenylamine-based dyes for dye-sensitized solar cells

Bakhytzhan Baptayev, Se Mi Kim, Bexultan Bolatbek, Sang Hee Lee, Mannix P. Balanay

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The effect of di-anchoring group was studied using 9,9-dioctyl-9H-fluorene as bridge which was formed by coupling two triphenylamine-based dyes. Two octyl chains were introduced into the core of di-anchoring dye to avoid its aggregation and minimize its TiO2/electrolyte recombination reactions. The photophysical, electrochemical and photovoltaic parameters of both mono- and di-anchoring sensitizers were compared, herein referred to as KS-18 and KS-20, respectively. Computational results indicated that the two anchoring groups adsorbed to the TiO2 in KS-20 were thermodynamically stable as compared to only one anchoring group. The results show that KS-20 produced a 7% increase in its photovoltaic conversion efficiency mainly due to an increase in the short-circuit current density. This increase was brought by the red-shifting and widening of its absorption spectra thereby increasing its light harvesting efficiency.

Original languageEnglish
Article number110020
JournalDyes and Pigments
Volume198
DOIs
Publication statusPublished - Feb 2022

Keywords

  • Coupling
  • Density functional theory
  • Fluorene
  • Self-consistent charge density functional tight binding
  • Triphenylamine

ASJC Scopus subject areas

  • General Chemical Engineering
  • Process Chemistry and Technology

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