Abstract
A technique of hydrophobic surface design with a high degree of structural homogeneity has been developed for catalytic materials. Mesoporous activated carbons and silica gel were modified by (A) treatment with vinyl-trimethoxysilane (vtms) or (B) chlorination with carbon tetrachloride followed by reaction with a Grignard reagent. Evidence for silica gel modification was obtained from FT-IR and 13C NMR spectroscopy and from elemental analysis. Carbons chemically modified with alkanes and olefins were studied using thermogravimetry (TG) and the results compared with those for the modified silica gel. TG and differential scanning calorimetry (DSC) revealed that the polymerisation of vinyl groups occurred on the carbon surface. The participation of the carrier surface in the initiation of radical processes has been discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 55-64 |
| Number of pages | 10 |
| Journal | Adsorption Science and Technology |
| Volume | 18 |
| Issue number | 1 |
| Publication status | Published - 2000 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemistry (miscellaneous)
- Process Chemistry and Technology
- Physical and Theoretical Chemistry
- Chemical Engineering(all)
Cite this
The hydrophobisation of activated carbon surfaces by organic functional groups. / Budarin, Vitaly L.; Clark, James H.; Mikhalovsky, Sergey V.; Gorlova, Alina A.; Boldyreva, Nataly A.; Yatsimirsky, Vitaly K.
In: Adsorption Science and Technology, Vol. 18, No. 1, 2000, p. 55-64.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - The hydrophobisation of activated carbon surfaces by organic functional groups
AU - Budarin, Vitaly L.
AU - Clark, James H.
AU - Mikhalovsky, Sergey V.
AU - Gorlova, Alina A.
AU - Boldyreva, Nataly A.
AU - Yatsimirsky, Vitaly K.
PY - 2000
Y1 - 2000
N2 - A technique of hydrophobic surface design with a high degree of structural homogeneity has been developed for catalytic materials. Mesoporous activated carbons and silica gel were modified by (A) treatment with vinyl-trimethoxysilane (vtms) or (B) chlorination with carbon tetrachloride followed by reaction with a Grignard reagent. Evidence for silica gel modification was obtained from FT-IR and 13C NMR spectroscopy and from elemental analysis. Carbons chemically modified with alkanes and olefins were studied using thermogravimetry (TG) and the results compared with those for the modified silica gel. TG and differential scanning calorimetry (DSC) revealed that the polymerisation of vinyl groups occurred on the carbon surface. The participation of the carrier surface in the initiation of radical processes has been discussed.
AB - A technique of hydrophobic surface design with a high degree of structural homogeneity has been developed for catalytic materials. Mesoporous activated carbons and silica gel were modified by (A) treatment with vinyl-trimethoxysilane (vtms) or (B) chlorination with carbon tetrachloride followed by reaction with a Grignard reagent. Evidence for silica gel modification was obtained from FT-IR and 13C NMR spectroscopy and from elemental analysis. Carbons chemically modified with alkanes and olefins were studied using thermogravimetry (TG) and the results compared with those for the modified silica gel. TG and differential scanning calorimetry (DSC) revealed that the polymerisation of vinyl groups occurred on the carbon surface. The participation of the carrier surface in the initiation of radical processes has been discussed.
UR - http://www.scopus.com/inward/record.url?scp=0034067540&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0034067540&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0034067540
VL - 18
SP - 55
EP - 64
JO - Adsorption Science and Technology
JF - Adsorption Science and Technology
SN - 0263-6174
IS - 1
ER -