Thin film growth by energetic cluster impact (ECI)

comparison between experiment and molecular dynamics simulations

Hellmut Haberland, Zinetulla Insepov, Martin Karrais, Martin Mall, Michael Moseler, Yonca Thurner

Research output: Contribution to journalArticle

30 Citations (Scopus)

Abstract

A new type of cluster ion source has been developed for thin film formation by accelerated metal cluster ions. Roughly one third of the clusters are neutral, the others positively or negatively charged. The clusters are accelerated by an electric field, and deposited onto a surface. If the kinetic energy is higher than about 5 keV for a cluster of about 1000 atoms, highly reflecting, strongly adhering thin films are formed on room temperature, uncleaned substrates. Mechanical stress in the film is small. No columnar or recrystallized thin film growth is observed, so that the film morphology does not fit the structure zone model of Movchan, Demchishin, and Thornton. Langevin molecular dynamics simulations give the following physical picture. A tiny, very high temperature spot is formed at each impact. This anneals the area around the impact zone and gives rise to near epitaxial growth. The main advantage of the method seems to be that dense films without columnar voids can be produced on room temperature substrates. The name energetic cluster impact (ECI) is proposed for this method.

Original languageEnglish
Pages (from-to)31-36
Number of pages6
JournalMaterials Science and Engineering B: Solid-State Materials for Advanced Technology
Volume19
Issue number1-2
DOIs
Publication statusPublished - Apr 19 1993
Externally publishedYes

Fingerprint

Film growth
Molecular dynamics
molecular dynamics
Thin films
Computer simulation
thin films
simulation
Experiments
Ion sources
Substrates
Epitaxial growth
Kinetic energy
Temperature
Metals
Electric fields
Ions
room temperature
metal clusters
Atoms
ion sources

ASJC Scopus subject areas

  • Materials Science(all)
  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

Cite this

Thin film growth by energetic cluster impact (ECI) : comparison between experiment and molecular dynamics simulations. / Haberland, Hellmut; Insepov, Zinetulla; Karrais, Martin; Mall, Martin; Moseler, Michael; Thurner, Yonca.

In: Materials Science and Engineering B: Solid-State Materials for Advanced Technology, Vol. 19, No. 1-2, 19.04.1993, p. 31-36.

Research output: Contribution to journalArticle

@article{8c815ae81eb34188999b848b8a712025,
title = "Thin film growth by energetic cluster impact (ECI): comparison between experiment and molecular dynamics simulations",
abstract = "A new type of cluster ion source has been developed for thin film formation by accelerated metal cluster ions. Roughly one third of the clusters are neutral, the others positively or negatively charged. The clusters are accelerated by an electric field, and deposited onto a surface. If the kinetic energy is higher than about 5 keV for a cluster of about 1000 atoms, highly reflecting, strongly adhering thin films are formed on room temperature, uncleaned substrates. Mechanical stress in the film is small. No columnar or recrystallized thin film growth is observed, so that the film morphology does not fit the structure zone model of Movchan, Demchishin, and Thornton. Langevin molecular dynamics simulations give the following physical picture. A tiny, very high temperature spot is formed at each impact. This anneals the area around the impact zone and gives rise to near epitaxial growth. The main advantage of the method seems to be that dense films without columnar voids can be produced on room temperature substrates. The name energetic cluster impact (ECI) is proposed for this method.",
author = "Hellmut Haberland and Zinetulla Insepov and Martin Karrais and Martin Mall and Michael Moseler and Yonca Thurner",
year = "1993",
month = "4",
day = "19",
doi = "10.1016/0921-5107(93)90161-F",
language = "English",
volume = "19",
pages = "31--36",
journal = "Materials Science and Engineering B: Solid-State Materials for Advanced Technology",
issn = "0921-5107",
publisher = "Elsevier",
number = "1-2",

}

TY - JOUR

T1 - Thin film growth by energetic cluster impact (ECI)

T2 - comparison between experiment and molecular dynamics simulations

AU - Haberland, Hellmut

AU - Insepov, Zinetulla

AU - Karrais, Martin

AU - Mall, Martin

AU - Moseler, Michael

AU - Thurner, Yonca

PY - 1993/4/19

Y1 - 1993/4/19

N2 - A new type of cluster ion source has been developed for thin film formation by accelerated metal cluster ions. Roughly one third of the clusters are neutral, the others positively or negatively charged. The clusters are accelerated by an electric field, and deposited onto a surface. If the kinetic energy is higher than about 5 keV for a cluster of about 1000 atoms, highly reflecting, strongly adhering thin films are formed on room temperature, uncleaned substrates. Mechanical stress in the film is small. No columnar or recrystallized thin film growth is observed, so that the film morphology does not fit the structure zone model of Movchan, Demchishin, and Thornton. Langevin molecular dynamics simulations give the following physical picture. A tiny, very high temperature spot is formed at each impact. This anneals the area around the impact zone and gives rise to near epitaxial growth. The main advantage of the method seems to be that dense films without columnar voids can be produced on room temperature substrates. The name energetic cluster impact (ECI) is proposed for this method.

AB - A new type of cluster ion source has been developed for thin film formation by accelerated metal cluster ions. Roughly one third of the clusters are neutral, the others positively or negatively charged. The clusters are accelerated by an electric field, and deposited onto a surface. If the kinetic energy is higher than about 5 keV for a cluster of about 1000 atoms, highly reflecting, strongly adhering thin films are formed on room temperature, uncleaned substrates. Mechanical stress in the film is small. No columnar or recrystallized thin film growth is observed, so that the film morphology does not fit the structure zone model of Movchan, Demchishin, and Thornton. Langevin molecular dynamics simulations give the following physical picture. A tiny, very high temperature spot is formed at each impact. This anneals the area around the impact zone and gives rise to near epitaxial growth. The main advantage of the method seems to be that dense films without columnar voids can be produced on room temperature substrates. The name energetic cluster impact (ECI) is proposed for this method.

UR - http://www.scopus.com/inward/record.url?scp=0027573441&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0027573441&partnerID=8YFLogxK

U2 - 10.1016/0921-5107(93)90161-F

DO - 10.1016/0921-5107(93)90161-F

M3 - Article

VL - 19

SP - 31

EP - 36

JO - Materials Science and Engineering B: Solid-State Materials for Advanced Technology

JF - Materials Science and Engineering B: Solid-State Materials for Advanced Technology

SN - 0921-5107

IS - 1-2

ER -