Three-dimensionally ordered macro/mesoporous TiO2 matrix to immobilize sulfur for high performance lithium/sulfur batteries

Chunyong Liang, Xiaomin Zhang, Yan Zhao, Taizhe Tan, Yongguang Zhang, Zhumabay Bakenov

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A three-dimensionally (3D) ordered macro-/mesoporous TiO2 (3DOM-mTiO2) was synthesized via a simple solvothermal process. 3DOM-mTiO2 was used as a sulfur carrier for cathode materials in a lithium-sulfur (Li-S) battery. The orderly interconnected macro and mesopores structure within the macropore walls yield a large pore volume and high specific surface area in 3DOM-mTiO2, which improved the sulfur loading capacity of the material. The S/TiO2 composite was synthesized as a cathode material for lithium/sulfur battery, which initially produced a high capacity of 1089 mAh g-1 and retained a value of 703 mAh g-1 after 200 cycles. An initial current rate of 0.2 C was used, which was further increased up to 2.5 C when a reversible capacity of 651 mAh g-1 was obtained. The excellent electrochemical performance can be attributed to the 3D ordered macro-/mesoporous structure of TiO2, which physically confines the soluble lithium polysulfides and diminishes the sulfur volume expansion upon cycling. In addition, the strong electrostatic attraction between the Ti-O bond and polysulfide stimulates the performance via stronger adsorption of the electrochemical reaction products.

Original languageEnglish
Article number415401
JournalNanotechnology
Volume29
Issue number41
DOIs
Publication statusPublished - Aug 3 2018

Fingerprint

Sulfur
Macros
Polysulfides
Cathodes
Reaction products
Lithium
Specific surface area
Electrostatics
Lithium sulfur batteries
Adsorption
Composite materials
polysulfide

Keywords

  • electrochemical performance
  • Li/S batteries
  • nanocomposites
  • TiO

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering
  • Electrical and Electronic Engineering

Cite this

Three-dimensionally ordered macro/mesoporous TiO2 matrix to immobilize sulfur for high performance lithium/sulfur batteries. / Liang, Chunyong; Zhang, Xiaomin; Zhao, Yan; Tan, Taizhe; Zhang, Yongguang; Bakenov, Zhumabay.

In: Nanotechnology, Vol. 29, No. 41, 415401, 03.08.2018.

Research output: Contribution to journalArticle

Liang, Chunyong ; Zhang, Xiaomin ; Zhao, Yan ; Tan, Taizhe ; Zhang, Yongguang ; Bakenov, Zhumabay. / Three-dimensionally ordered macro/mesoporous TiO2 matrix to immobilize sulfur for high performance lithium/sulfur batteries. In: Nanotechnology. 2018 ; Vol. 29, No. 41.
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