Unraveling the Ã1B1 ← X̃ 1A1 spectrum of CCl2

The Renner-Teller effect, barrier to linearity, and vibrational analysis using an effective polyad hamiltonian

Craig Richmond, Chong Tao, Calvin Mukarakate, Haiyan Fan, Klaas Nauta, Timothy W. Schmidt, Scott H. Kable, Scott A. Reid

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

We report studies aimed at unraveling the complicated structure of the CCl2 Ã1B1 ← X̃ 1A1 system. We have remeasured the fluorescence excitation spectrum from ∼17 500 to 24 000 cm-1 and report the term energies and A rotational constants of many new bands for both major isotopologues (C35Cl2, C35Cl37Cl). We fit the observed term energies to a polyad effective Hamiltonian model and demonstrate that a single resonance term accounts for much of the observed mixing, which begins ∼1300 cm-1 above the vibrationless level of the Ã1B1 state. The derived à 1B1 vibrational parameters are in excellent agreement with ab initio predictions, and the mixing coefficients deduced from the polyad model fit are in close agreement with those derived from direct fits of single vibronic level (SVL) emission intensities. The approach to linearity and thus the Renner-Teller (RT) intersection is probed through the energy dependence of the A rotational constant and fluorescence lifetime measurements, which indicate a barrier height above the vibrationless level of the X̃1A 1 state of ∼23 000-23 500 cm-1, in excellent agreement with ab initio theory.

Original languageEnglish
Pages (from-to)11355-11362
Number of pages8
JournalJournal of Physical Chemistry A
Volume112
Issue number45
DOIs
Publication statusPublished - Nov 13 2008
Externally publishedYes

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Hamiltonians
linearity
Fluorescence
fluorescence
intersections
energy
life (durability)
coefficients
predictions
excitation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Unraveling the Ã1B1 ← X̃ 1A1 spectrum of CCl2 : The Renner-Teller effect, barrier to linearity, and vibrational analysis using an effective polyad hamiltonian. / Richmond, Craig; Tao, Chong; Mukarakate, Calvin; Fan, Haiyan; Nauta, Klaas; Schmidt, Timothy W.; Kable, Scott H.; Reid, Scott A.

In: Journal of Physical Chemistry A, Vol. 112, No. 45, 13.11.2008, p. 11355-11362.

Research output: Contribution to journalArticle

Richmond, Craig ; Tao, Chong ; Mukarakate, Calvin ; Fan, Haiyan ; Nauta, Klaas ; Schmidt, Timothy W. ; Kable, Scott H. ; Reid, Scott A. / Unraveling the Ã1B1 ← X̃ 1A1 spectrum of CCl2 : The Renner-Teller effect, barrier to linearity, and vibrational analysis using an effective polyad hamiltonian. In: Journal of Physical Chemistry A. 2008 ; Vol. 112, No. 45. pp. 11355-11362.
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