Vibrational mode selectivity in hyperfine interactions: Polarization quantum beat spectroscopy of HCF (Ã1 A″)

Ionela Ionescu, Haiyan Fan, Chris Annesley, Ju Xin, Scott A. Reid

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

The initial results concerning the vibrational mode dependence of the 19F and 1H hyperfine interaction in HCF(Ã1A″) were reported. As such, the 19F nuclear spin/overall rotation coupling constants display a pronounced energy and mode selectivity which was reasonably explained in terms of variations in both the rotational constant A and nuclear spin/electron orbital coupling constant A. It was anticipated that Zeeman measurements in combination with such results will provide a detailed glimpse into the electronic structure of this prototypical carbene.

Original languageEnglish
Pages (from-to)1164-1167
Number of pages4
JournalJournal of Chemical Physics
Volume120
Issue number3
DOIs
Publication statusPublished - Jan 15 2004

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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