Abstract
The initial results concerning the vibrational mode dependence of the 19F and 1H hyperfine interaction in HCF(Ã1A″) were reported. As such, the 19F nuclear spin/overall rotation coupling constants display a pronounced energy and mode selectivity which was reasonably explained in terms of variations in both the rotational constant A and nuclear spin/electron orbital coupling constant A. It was anticipated that Zeeman measurements in combination with such results will provide a detailed glimpse into the electronic structure of this prototypical carbene.
| Original language | English |
|---|---|
| Pages (from-to) | 1164-1167 |
| Number of pages | 4 |
| Journal | Journal of Chemical Physics |
| Volume | 120 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Jan 15 2004 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
Vibrational mode selectivity in hyperfine interactions : Polarization quantum beat spectroscopy of HCF (Ã1 A″). / Ionescu, Ionela; Fan, Haiyan; Annesley, Chris; Xin, Ju; Reid, Scott A.
In: Journal of Chemical Physics, Vol. 120, No. 3, 15.01.2004, p. 1164-1167.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Vibrational mode selectivity in hyperfine interactions
T2 - Polarization quantum beat spectroscopy of HCF (Ã1 A″)
AU - Ionescu, Ionela
AU - Fan, Haiyan
AU - Annesley, Chris
AU - Xin, Ju
AU - Reid, Scott A.
PY - 2004/1/15
Y1 - 2004/1/15
N2 - The initial results concerning the vibrational mode dependence of the 19F and 1H hyperfine interaction in HCF(Ã1A″) were reported. As such, the 19F nuclear spin/overall rotation coupling constants display a pronounced energy and mode selectivity which was reasonably explained in terms of variations in both the rotational constant A and nuclear spin/electron orbital coupling constant A. It was anticipated that Zeeman measurements in combination with such results will provide a detailed glimpse into the electronic structure of this prototypical carbene.
AB - The initial results concerning the vibrational mode dependence of the 19F and 1H hyperfine interaction in HCF(Ã1A″) were reported. As such, the 19F nuclear spin/overall rotation coupling constants display a pronounced energy and mode selectivity which was reasonably explained in terms of variations in both the rotational constant A and nuclear spin/electron orbital coupling constant A. It was anticipated that Zeeman measurements in combination with such results will provide a detailed glimpse into the electronic structure of this prototypical carbene.
UR - http://www.scopus.com/inward/record.url?scp=1142279659&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=1142279659&partnerID=8YFLogxK
U2 - 10.1063/1.1640994
DO - 10.1063/1.1640994
M3 - Article
VL - 120
SP - 1164
EP - 1167
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 3
ER -