Abstract
The initial results concerning the vibrational mode dependence of the 19F and 1H hyperfine interaction in HCF(Ã1A″) were reported. As such, the 19F nuclear spin/overall rotation coupling constants display a pronounced energy and mode selectivity which was reasonably explained in terms of variations in both the rotational constant A and nuclear spin/electron orbital coupling constant A. It was anticipated that Zeeman measurements in combination with such results will provide a detailed glimpse into the electronic structure of this prototypical carbene.
Original language | English |
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Pages (from-to) | 1164-1167 |
Number of pages | 4 |
Journal | Journal of Chemical Physics |
Volume | 120 |
Issue number | 3 |
DOIs | |
Publication status | Published - Jan 15 2004 |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry