Wet chemistry synthesis of β-nickel aluminide NiAl

Helmut Bönnemann, Werner Brijoux, Hans Werner Hofstadt, Teyeb Ould-Ely, Wolfgang Schmidt, Bernd Waßmuth, Claudia Weidenthaler

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A fine powder of β-nickel aluminide NiAl is obtained by reaction of [Ni(cod)2] (cod = cycloocta-1,5-diene) with AlEt3 in toluene at room temperature and under a H2 pressure of 5-10 MPa and subsequent distillation of the solvent, subsequent hydrogenation (0.1-5 MPa), and annealing (200°C) [Eq. (a)]. This novel wet chemistry synthesis of aluminides may be transferred to Ni3Al (α-nickel aluminide) and ternary aluminide powders such as GaNiAl, FeNiAl, and CeNiAl.

Original languageEnglish
Pages (from-to)599-603
Number of pages5
JournalAngewandte Chemie - International Edition
Issue number4
Publication statusPublished - Feb 15 2002


  • Aluminum
  • Intermetallic phases
  • Metal-metal interactions
  • Nickel
  • Solid-state structures

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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  • Cite this

    Bönnemann, H., Brijoux, W., Hofstadt, H. W., Ould-Ely, T., Schmidt, W., Waßmuth, B., & Weidenthaler, C. (2002). Wet chemistry synthesis of β-nickel aluminide NiAl. Angewandte Chemie - International Edition, 41(4), 599-603.